Gilmarite

Cu2+3(AsO4)(OH)3
IMA status
  • Approved
IMA symbol
Gmr
Also known as
  • Gilmariet
  • IMA1996-017

Where it forms, where it's found

Type locality
Roua Mines (Clue de Roua)
  1. Daluis
  2. Nice Arrondissement
  3. Alpes-Maritimes
  4. Provence-Alpes-Côte d'Azur
  5. France

44.0304°, 6.8677°

10recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Greenish blue
Streak
Greenish blue
Tenacity
brittle
Cleavage
Distinct/Good

Good on (010).

Fracture
Irregular/Uneven
Density
4.2 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 77° · 2V calc = 80°
Refractive index
1.76 – 1.83
Surface relief
High
Principal indices
nα 1.760 · nβ 1.80 · nγ 1.83
Pleochroism
Weak

X = Y = light green; Z = green

Dispersion
r > v
Extinction
On {010}, X ∧ c = 33° and Y ∧ a = 37.1°; on {001}, Y ∧ a = 34.3° and Z ∧ b = 30.1°; on {101}, Z ∧ b = 44◦ and Y′ ∧ [101] = 36.5°.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0700
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]700 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation700 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#1
Cell parameters
a = 5.445(4) Å · b = 5.873(3) Å · c = 5.104(3) Å
Cell angles
α = 114.95(3) ° · β = 93.05(5) ° · γ = 91.92(4) °
Ratio a:b:c
1 : 1.079 : 0.937
Z
1
Morphology

Lozenge-shaped crystals, typically in rosettes. Type material crystals are elongated along [101] or [100] and flattened on (010). The most developed forms are (100), (010), (001) and (101).

Twinning

Not twinned.

Type-locality form

Rosettes (0.3 mm diameter) and isolated crystals (0.1 × 0.04 × 0.02 mm maximum dimension).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper363.546190.638
50.09%
8OOxygenOxygen715.999111.993
29.43%
33AsArsenicArsenic174.92274.922
19.69%
1HHydrogenHydrogen31.0083.024
0.79%
Total380.577100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Gilmariet
  • IMA1996-017

In other languages

German
Gilmarit · IMA 1996-017
Italian
Gilmarite
Chinese
三斜光线石

Classification

Strunz
10th ed.

8.BE.25

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BEWith only medium-sized cations, (OH, etc.):RO4 > 2:1Group
  • 8.BE.25GilmariteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1999Sarp, Haul, Černý, Radovan (1999) Gilmarite, Cu3(AsO4)(OH)3, a new mineral: its description and crystal structure. European Journal of Mineralogy, 11 (3) 549-556 doi:10.1127/ejm/11/3/0549 DOI: 10.1127/ejm/11/3/0549
  2. 2005(2005) Gilmarite. Handbook of Mineralogy. Mineralogical Society of America
  3. 2007Kolitsch, U.; Gröbner, J.; Blaß, G.; Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6). 19-23; 70
  4. 2016Vrtiška, L., Števko, M., Sejkora, J., Malíková, R. (2016) Gilmarite, triclinic Cu3(AsO4)(OH)3, from Běloves near Náchod - the first occurrence in Czech Republic. Bulletin Mineralogicko-Petrologickeho Oddeleni Narodniho Muzea v Praze: 22: 230-233.
  5. 2017Krivovichev, S. V. (2017) Hydrogen bonding and structural complexity of the Cu3(AsO4)(OH)3 polymorphs (clinoclase, gilmarite): a theoretical study. Journal of GEOsciences, 62 (2) 79-85
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Gilmarite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/gilmarite-6970},
  note      = {Accessed 2026-05-11}
}