Grimaldiite

CrO(OH)
IMA status
  • Approved
IMA symbol
Gmd
Discovered
1967
Also known as
  • Grimaldiiet
  • Grimaldite
  • IMA1967-036

Where it forms, where it's found

Geological setting

Alluvial gravels

Type locality
Merume River
  1. Rest of Region 8
  2. Potaro-Siparuni Region
  3. Guyana

5.2667°, -59.8333°

6recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Deep red to pinkish brown
Cleavage
Distinct/Good

(0001)

Density
4.11 g/cm³

Optical

Optical type
Uniaxial
Refractive index
1.975 – 2.155
Surface relief
Very high
Principal indices
nω 2.155 · nε 1.975
Notes

n = ∼2.05, varies in mixtures

Michel-Lévy diagramhighlighted lineδ = 0.1800
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1800 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1800 nm
Order4th order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#86
Cell parameters
a = 2.973(2) Å · c = 13.392(1) Å
Z
3
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
24CrChromiumChromium151.99651.996
61.17%
8OOxygenOxygen215.99931.998
37.64%
1HHydrogenHydrogen11.0081.008
1.19%
Total85.002100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Grimaldiiet
  • Grimaldite
  • IMA1967-036

In other languages

German
Grimaldiit · IMA 1967-036
Spanish
Grimaldiíta
Italian
Grimaldiite
Chinese
三方羟铬矿

Classification

Strunz
10th ed.

4.FE.20

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FEHydroxides with OH, without H2O; sheets of edge-sharing octahedraGroup
  • 4.FE.20GrimaldiiteSpecies
Dana
8th ed.

06.01.05.01

  • 06Hydroxides and Oxides Containing HydroxylClass
  • 06.01XO(OH)Type
  • 06.01.05— unnamed intermediate level —Group
  • 06.01.05.01GrimaldiiteSpecies
CIM

7.14.3

  • 7Oxides and HydroxidesClass
  • 7.14Oxides of CrGroup
  • 7.14.3GrimaldiiteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. American Mineralogist: 62: 593.
  2. 1976Milton, C., Appleman, D. E., Appleman, M. H., Chao, E. C. T., Cuttitta, F., Dinnin, J. I., Dwornik, E. J., Ingram, B. L. and Rose, H. J., Jr. (1976) Merumite, a complex assemblage of chromium minerals from Guyana. U.S. Geological Survey Professional Paper 887: 1-29.
  3. 1984Livingstone, A., Jackson, B., Davidson, P. J. (1984) Grimaldiite, CrOOH, a second occurrence, from the Hiaca Mine, Colquechaca, Bolivia. Mineralogical Magazine, 48 (349) 560-562 doi:10.1180/minmag.1984.048.349.16 DOI: 10.1180/minmag.1984.048.349.16
  4. 2005(2005) Grimaldiite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2016Burlet, C., Goethals, H., Vanbrabant, Y. (2016) Delafossite structure of heterogenite polytypes (HCoO2) by Raman and infrared micro-spectroscopy. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 159. 90-97 doi:10.1016/j.saa.2016.01.038DOI: 10.1016/j.saa.2016.01.038
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Grimaldiite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/grimaldiite-1750},
  note      = {Accessed 2026-05-11}
}