Guyanaite

CrO(OH)
IMA status
  • Approved
IMA symbol
Guy
Discovered
1967
Also known as
  • Guyanaiet
  • IMA1967-034

Where it forms, where it's found

Geological setting

In an alluvial placer deposit, in fine-grained intergrowth with other chromium oxide-hydroxide minerals

Type locality
Merume River
  1. Rest of Region 8
  2. Potaro-Siparuni Region
  3. Guyana

5.2667°, -59.8333°

5recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Translucent
Colour
Reddish brown · golden brown · greenish brown · green

probably variable with particle size and degree of oxidation;

Streak
Yellow-brown, greenish brown
Density
4.67 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.9
Surface relief
Very high
Principal indices
nβ 1.9
Pleochroism
Weak

brown colours

Dispersion
r > v extreme
Optical colour
gray with greenish tint
Internal reflections
strong red to yellowish brown

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 4.860(3) Å · b = 4.305(10) Å · c = 2.954(4) Å
Ratio a:b:c
1 : 0.886 : 0.608
Z
2
Type-locality form

microcrystalline aggregates, alluvial grains; very rarely as prismatic crystals, up to 0.1 mm

Comment

Space group is P21nm or Pnnm (LP phase); HP phase: Pnnm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
24CrChromiumChromium151.99651.996
61.17%
8OOxygenOxygen215.99931.998
37.64%
1HHydrogenHydrogen11.0081.008
1.19%
Total85.002100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Al
  • V

Synonyms

  • Guyanaiet
  • IMA1967-034

In other languages

German
Guyanait · IMA 1967-034
Italian
Guyanaite

Classification

Strunz
10th ed.

4.FD.10

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FDHydroxides with OH, without H2O; chains of edge-sharing octahedraGroup
  • 4.FD.10GuyanaiteSpecies
Dana
8th ed.

06.01.02.03

  • 06Hydroxides and Oxides Containing HydroxylClass
  • 06.01XO(OH)Type
  • 06.01.02Boehmite GroupGroup
  • 06.01.02.03GuyanaiteSpecies
CIM

7.14.4

  • 7Oxides and HydroxidesClass
  • 7.14Oxides of CrGroup
  • 7.14.4GuyanaiteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1976Milton, C., Appleman, D. E., Appleman, M. H., Chao, E. C. T., Cuttitta, F., Dinnin, J. I., Dwornik, E. J., Ingram, B. L. and Rose, H. J., Jr. (1976) Merumite, a complex assemblage of chromium minerals from Guyana. U.S. Geological Survey Professional Paper 887: 1-29.
  2. 1976Christensen, N., Hansen, P., Lehmann, M.S. (1976) Isotope effects in the bonds of β-CrOOH and β-CrOOD. Journal of Solid State Chemistry: 19: 299-304.
  3. 1977Fleischer, Michael, Cabri, Louis J., Nickel, Ernest H., Pabst, Adolf (1977) New Mineral Names. American Mineralogist, 62 (5-6) 593-600
  4. 2005(2005) Guyanaite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2012Jahn, S., Wunder, B., Koch-Müller, M., Tarrieu, L., Pöhle, M., Watenphul, A., Taran, M.N. (2012) Pressure-induced hydrogen bond symmetrisation in guyanaite, β-CrOOH: evidence from spectroscopy and ab initio simulations. European Journal of Mineralogy: 24(5): 839-850.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Guyanaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/guyanaite-1783},
  note      = {Accessed 2026-05-11}
}