Guérinite

Ca5(AsO3OH)2(AsO4)2 · 9H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Gué
Also known as
  • Guériniet

Where it forms, where it's found

Geological setting

Post-mine

Type locality
Daniel Mine (St. Daniel Mine)
  1. Neustädtel
  2. Schneeberg
  3. Erzgebirgskreis
  4. Saxony
  5. Germany

50.5789°, 12.6161°

39recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789101.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colorless
Streak
White
Tenacity
brittle
Cleavage

Three directions of cleavage mentioned, but not described.

Density
2.68 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 7 – 5°
Refractive index
1.574 – 1.584
Surface relief
Moderate
Principal indices
nα 1.574 – 1.576 · nβ 1.582 · nγ 1.582 – 1.584
Birefringence
0.008
Pleochroism
Non-pleochroic
Dispersion
r > v strong, also r < v
Extinction
Z=elongation
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]80 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation80 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 17.631(2) Å · b = 6.731(1) Å · c = 23.388(3) Å
Cell angles
β = 90.69(1) °
Ratio a:b:c
1 : 0.382 : 1.327
Comment

Space-group setting P21/n. For synthetic material, Catti & Ferraris (1974) give: P21/n, a 17.63(1), b 6.734(3), c 23.47(2) Å, β 90.6(1)°.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2515.999399.975
43.46%
33AsArsenicArsenic474.922299.688
32.57%
20CaCalciumCalcium540.078200.390
21.78%
1HHydrogenHydrogen201.00820.160
2.19%
Total920.213100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Guériniet

In other languages

German
Guérinit
Italian
Guérinite

Classification

Strunz
10th ed.

8.CJ.75

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CJWith only large cationsGroup
  • 8.CJ.75GuériniteSpecies
Dana
8th ed.

39.02.02.02

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.02(AB)5[HXO4]2[XO4]2.xH2OType
  • 39.02.02— unnamed intermediate level —Group
  • 39.02.02.02GuériniteSpecies
CIM

20.2.11

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.2Arsenates of Be, Mg, Ca or BaGroup
  • 20.2.11GuériniteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. American Mineralogist: 47: 416.
  2. 1964Pierrot, Roland (1964) Contribution à la minéralogie des arséniates calciques et calcomagnésiens naturels. Bulletin de Minéralogie, 87 (2) 169-211 doi:10.3406/bulmi.1964.5727DOI: 10.3406/bulmi.1964.5727
  3. 1965American Mineralogist (1965): 50: 812.
  4. 1974Catti, M., Ferraris, G. (1974) Crystal structure of Ca5(HAsO4)2(AsO4)2.9H2O (guérinite). Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 30 (7). 1789-1794 doi:10.1107/s0567740874005814DOI: 10.1107/s0567740874005814
  5. 2005(2005) Guérinite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Guérinite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/guerinite-1767},
  note      = {Accessed 2026-05-11}
}