Hannayite

(NH4)2Mg3(PO3OH)4 · 8H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Han
Discovered
1878
Also known as
  • Hannayiet

Where it forms, where it's found

Geological setting

Guano derived mineral crusts in caves.

Type locality
Skipton Caves
  1. Mount Widderin
  2. Skipton
  3. Corangamite Shire
  4. Victoria
  5. Australia

-37.7370°, 143.3478°

9recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Light yellow · colourless in transmitted light.
Cleavage
Distinct/Good

On (001), complete; on (110), (110) and (130), poor.

Density
1.893 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 45 – 90° · 2V calc = 64 – 86°
Refractive index
1.504 – 1.579
Surface relief
Moderate
Principal indices
nα 1.504 – 1.555 · nβ 1.522 – 1.572 · nγ 1.539 – 1.579
Dispersion
Relatively weak r < v
Michel-Lévy diagramhighlighted lineδ = 0.0295
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]295 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation295 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 7.70 Å · b = 11.51 Å · c = 6.70 Å
Cell angles
α = 76 ° · β = 99.8 ° · γ = 115.8 °
Ratio a:b:c
1 : 1.495 : 0.870
Morphology

Crystals small and slender, elongated [001] and striated parallel to it. Tabular to 12mm, radial sprays of laths.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
60.28%
15PPhosphorusPhosphorus430.974123.896
19.45%
12MgMagnesiumMagnesium324.30572.915
11.44%
1HHydrogenHydrogen281.00828.224
4.43%
7NNitrogenNitrogen214.00728.014
4.40%
Total637.025100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Hannayiet

In other languages

German
Hannayit
Italian
Hannayite

Classification

Strunz
10th ed.

8.CH.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CHWith large and medium-sized cations, RO4:H2O < 1:1Group
  • 8.CH.35HannayiteSpecies
Dana
8th ed.

39.03.05.01

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.03MiscellaneousType
  • 39.03.05— unnamed intermediate level —Group
  • 39.03.05.01HannayiteSpecies
CIM

19.3.24

  • 19PhosphatesClass
  • 19.3Phosphates of Be and MgGroup
  • 19.3.24HannayiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1878Ulrich and vom Rath (1878) Berichte Niederrheinische Gesellschaft für Natur und Heilkunde, Bonn: 35, january 7: 11.
  2. 1879Ulrich and vom Rath (1879) Berichte Niederrheinische Gesellschaft für Natur und Heilkunde, Bonn: 36, January 13: 5.
  3. 1918(1918) Atlas Der Krystallformen Vol. 4 - Text - Band IV - Fergusonit-Ixionolith. Carl Winters Universitätsbuchhandlung, Heidelberg.
  4. 1921Larsen, E.S. (1921) The Microscopic Determination of the Nonopaque Minerals, First edition, USGS Bulletin 679: 83 (identity of material as Hannayite uncertain).
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hannayite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hannayite-1816},
  note      = {Accessed 2026-05-11}
}