Henritermierite

Ca3Mn3+2(SiO4)2(OH)4
IMA status
  • Approved
IMA symbol
Hri
Discovered
1968
IMA approved
1968
Also known as
  • Henritermieriet
  • IMA1968-029

Where it forms, where it's found

Geological setting

Manganese deposits

Type locality
Tachgagalt Mine
  1. Tansifte Caïdat
  2. Agdz Cercle
  3. Zagora Province
  4. Drâa-Tafilalet Region
  5. Morocco

30.7833°, -6.8500°

5recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Translucent
Colour
Clove-brown to apricot-brown · lemon-yellow to pale yellow in thin section.
Streak
White
Fracture
Conchoidal
Density
3.34 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.765 – 1.8
Surface relief
High
Principal indices
nω 1.765 · nε 1.8
Pleochroism
Weak

O = very pale yellow E = lemon-yellow

Michel-Lévy diagramhighlighted lineδ = 0.0350
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]350 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation350 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#177
Cell parameters
a = 12.39 Å · c = 11.91 Å
Z
8
Morphology

As pseudo-octahedral crystals, to 3mm, and as aggregates of small grains.

Twinning

Common on (101) sectored

Type-locality form

Aggregates of small grains up to 0.5 mm; mostly about 0.2 mm in diameter, filling interstices between crystals of marokite, hausmannite, and rare gaudefroyite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
39.81%
20CaCalciumCalcium340.078120.234
24.93%
25MnManganeseManganese254.938109.876
22.78%
14SiSiliconSilicon228.08556.170
11.65%
1HHydrogenHydrogen41.0084.032
0.83%
Total482.300100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe

Synonyms

  • Henritermieriet
  • IMA1968-029

In other languages

German
Henritermierit · IMA 1968-029
Italian
Henritermierite

Classification

Strunz
10th ed.

9.AD.25

  • 9SilicatesClass
  • 9.ANesosilicatesDivision
  • 9.ADNesosilicates without additional anions; cations in [6] and/or greater coordinationGroup
  • 9.AD.25HenritermieriteSpecies
Dana
8th ed.

51.04.04.01

  • 51Nesosilicates Insular Sio4 Groups OnlyClass
  • 51.04Insular SiO4 Groups Only with cations in [6] and >[6] coordinationType
  • 51.04.04Garnet group (Tetragonal Hydrogarnet)Group
  • 51.04.04.01HenritermieriteSpecies
CIM

16.16.19

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.16Aluminosilicates of MnGroup
  • 16.16.19HenritermieriteSpecies

Group, growth & confusion

In the same group
1 members

Literature, links & citation

Citations
  1. 1969Aubry, André, Dusausoy, Yves, Laffaille, Alain, Protas, Jean (1969) Détermination et étude de la structure cristalline de l'henritermiérite, hydrogrenat de symétrie quadratique. Bulletin de Minéralogie, 92 (2) 126-133 doi:10.3406/bulmi.1969.6330DOI: 10.3406/bulmi.1969.6330
  2. 1969Gaudefroy, Christophe, Orliac, Marcel, Permingeat, François, Parfenoff, Alexandre (1969) L'henritermiérite, une nouvelle espèce minérale. Bulletin de Minéralogie, 92 (2) 185-190 doi:10.3406/bulmi.1969.6335 DOI: 10.3406/bulmi.1969.6335
  3. 1969Fleischer, Michael (1969) New Mineral Names. American Mineralogist, 54 (11-12) 1737-1742
  4. 2001Armbruster, T., Kohler, T., Libowitzky, E., Friedrich, A., Miletich, R., Kunz, M., Medenbach, O., Gutzmer, J. (2001) Structure, compressibility, hydrogen bonding, and dehydration of the tetragonal Mn3+ hydrogarnet, henritermierite. American Mineralogist: 86: 147-158.
  5. 2001(2001) Henritermierite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Henritermierite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/henritermierite-1868},
  note      = {Accessed 2026-05-11}
}