Hephaistosite

TlPb2Cl5
IMA status
  • Approved
IMA symbol
Hep
IMA approved
2007
Also known as
  • Hephaistosiet
  • IMA2006-043

Where it forms, where it's found

Geological setting

High-temperature fumarole (~400°C), altered pyroclastic breccia.

Type locality
La Fossa crater
  1. Vulcano Island
  2. Lipari
  3. Eolie Islands (Aeolian Islands)
  4. Metropolitan City of Messina
  5. Sicily
  6. Italy

38.4034°, 14.9614°

2recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Density
5.932 g/cm³

Optical

UV response
Not fluorescent.
Notes

The mean index of refraction is 2.0(1).

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 8.9477(6) Å · b = 7.9218(7) Å · c = 12.4955(5) Å
Cell angles
β = 90.092(4) °
Ratio a:b:c
1 : 0.885 : 1.397
Morphology

Tabular on (010). Forms at the type location include: (010), (101), (110), (100), (001), and (011).

Type-locality form

Aggregates of pale yellow-green tabular crystals up to 0.1 mm in length.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead2207.200414.400
52.06%
81TlThalliumThallium1204.380204.380
25.67%
17ClChlorineChlorine535.450177.250
22.27%
Total796.030100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Hephaistosiet
  • IMA2006-043

In other languages

German
Hephaistosit · IMA 2006-043
Italian
hephaistosite

Classification

Strunz
10th ed.

3.AA.60

  • 3HalidesClass
  • 3.ASimple halides, without H2ODivision
  • 3.AAM:X = 1:1, 2:3, 3:5, etc.Group
  • 3.AA.60HephaistositeSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 2005Zelenski, Michael, Bortnikova, Svetlana (2005) Sublimate speciation at Mutnovsky volcano, Kamchatka. European Journal of Mineralogy, 17 (1) 107-118 doi:10.1127/0935-1221/2005/0017-107DOI: 10.1127/0935-1221/2005/0017-107
  2. 2008Campostrini, I., Demartin, F., Gramaccioli, C. M., Orlandi, P. (2008) Hephaistosite, TlPb2Cl5, a new thallium mineral series from La Fossa Crater, Vulcano, Aeolian Islands, Italy. The Canadian Mineralogist, 46 (3) 701-708 doi:10.3749/canmin.46.3.701 DOI: 10.3749/canmin.46.3.701
  3. 2009Mitolo, D., Pinto, D., Garavelli, A., Bindi, L., Vurro, F. (2009) The role of the minor substitutions in the crystal structure of natural challacolloite, KPb2Cl5, and hephaistosite, TlPb2Cl5, from Vulcano (Aeolian Archipelago, Italy) Mineralogy and Petrology, 96 (1) 121-128 doi:10.1007/s00710-008-0041-2DOI: 10.1007/s00710-008-0041-2
  4. 2011(2011) Hephaistosite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hephaistosite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hephaistosite-31407},
  note      = {Accessed 2026-05-11}
}