Hetaerolite

ZnMn3+2O4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Hta
Discovered
1877
Also known as
  • Hetaeroliet
  • Hetaerolit
  • Hetaerolite (of Moore)
  • +2 more

Where it forms, where it's found

Type locality
Passaic pit (Marshall Mine
  1. Passaic Mine)
  2. Sterling Hill
  3. Ogdensburg
  4. Sussex County
  5. New Jersey
  6. USA

41.0825°, -74.6061°

99recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Black · reddish-black
Streak
Dark brown
Tenacity
brittle
Cleavage
Poor/Indistinct

(001)

Fracture
Irregular/Uneven
Density
5.18 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
2.14 – 2.34
Surface relief
Very high
Principal indices
nω 2.34 · nε 2.14
UV response
Not fluorescent in ultraviolet
Michel-Lévy diagramhighlighted lineδ = 0.2000
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2000 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2000 nm
Order4th order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#178
Cell parameters
a = 5.72 Å · c = 9.24 Å
Morphology

Usually pseudo-octahedral, but may be rod-like and elongated.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese254.938109.876
45.92%
30ZnZincZinc165.38065.380
27.33%
8OOxygenOxygen415.99963.996
26.75%
Total239.252100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Hetaeroliet
  • Hetaerolit
  • Hetaerolite (of Moore)
  • Hetärolith
  • Zinc Hausmannite

In other languages

German
Hetaerolith
Spanish
Hetaerolita
Italian
Hetaerolite
Russian
гетеролит

Classification

Strunz
10th ed.

4.BB.10

  • 4OxidesClass
  • 4.BMetal: Oxygen = 3:4 and similarDivision
  • 4.BBWith only medium-sized cationsGroup
  • 4.BB.10HetaeroliteSpecies
Dana
8th ed.

07.02.07.02

  • 07Multiple OxidesClass
  • 07.02AB2X4Type
  • 07.02.07— unnamed intermediate level —Group
  • 07.02.07.02HetaeroliteSpecies
CIM

7.5.6

  • 7Oxides and HydroxidesClass
  • 7.5Oxides of Zn, Cd and HgGroup
  • 7.5.6HetaeroliteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1877Moore, G.E. (1877) Preliminary notice of the discovery of a new mineral species. American Journal of Science and Arts: 14: 423-423.
  2. 1914Ford, W. E.; Bradley, W. M. (1914) Über Hetärolith von Leadville, Colorado. Zeitschrift für Kristallographie, 53 (1-6). 219-224 doi:10.1524/zkri.1914.53.1.219DOI: 10.1524/zkri.1914.53.1.219
  3. 1935Palache, Charles (1935) The minerals of Franklin and Sterling Hill, Sussex County, New Jersey. Professional Paper 180. US Geological Survey 135 pp. doi:10.3133/pp180 DOI: 10.3133/pp180
  4. 1942Frondel, Clifford, Heinrich, E. Wm. (1942) New data on hetaerolite, hydrohetaerolite, coronadite and hollandite. American Mineralogist, 27 (1) 48-56
  5. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hetaerolite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hetaerolite-1883},
  note      = {Accessed 2026-05-11}
}