Hydrobiotite

K(Mg,Fe2+)6(Si,Al)8O20(OH)4 · nH2O
IMA status
  • Approved
IMA symbol
Hbt
Discovered
1882
Also known as
  • Hydrobiotiet
  • Ledikit
  • Ledikita
  • +6 more

Where it forms, where it's found

Geological setting

Alteration of mica.

36recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Blackish · brownish · golden yellow · pinkish.
Tenacity
flexible
Cleavage
Perfect

(001)

Density
2.49 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 10 – 13°
Refractive index
1.56 – 1.567
Surface relief
Moderate
Principal indices
nβ 1.560 – 1.562 · nγ 1.565 – 1.567
Pleochroism
Weak

X = light brown; Y = Z = brown.

Dispersion
weak
Notes

Absorption: X > Y = Z.

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
c = 25.0(5) Å
Comment

by analogy to biotite and vermiculite

Chemical composition

Impurities
  • Ti
  • Cr
  • Mn
  • Ca
  • Sr
  • Ba
  • Na
  • Rb
  • F
  • P

Synonyms

  • Hydrobiotiet
  • Ledikit
  • Ledikita
  • Ledikite
  • Philadelphit
  • Philadelphite
  • Voigtit
  • Voigtita
  • Voigtite

In other languages

German
Hydrobiotit
Italian
Hydrobiotite · Idrobiotite

Classification

Strunz
10th ed.

9.EC.60

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.ECPhyllosilicates with mica sheets, composed of tetrahedral and octahedral netsGroup
  • 9.EC.60HydrobiotiteSpecies
Dana
8th ed.

71.02.2d.01

  • 71Phyllosilicates Sheets of Six-membered RingsClass
  • 71.02Sheets of 6-membered rings with 2:1 layersType
  • 71.02.2d— unnamed intermediate level —Group
  • 71.02.2d.01HydrobiotiteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1882Schrauf, A. (1882) Beiträge zur kenntniss des Associationskreises der Magnesiasilicate. Zeitschrift für Krystallographie und Mineralogie, 6, 321-388.
  2. 1934Gruner, J.W. (1934) The structures of vermiculites and their collapse by dehydration. American Mineralogist, 19, 557-575.
  3. 1941Ruthruff, Robert F. (1941) Vermiculite and hydrobiotite. American Mineralogist, 26 (8) 478-484
  4. 1963COLEMAN, N. T., LEROUX, F. H., CADY, JOHN G. (1963) Biotite - Hydrobiotite - Vermiculite in Soils. Nature, 198 (4878). 409-410 doi:10.1038/198409c0DOI: 10.1038/198409c0
  5. 1966Boettcher, A. L. (1966) Vermiculite, hydrobiotite, and biotite in the Rainy Creek igneous complex near Libby, Montana. Clay Minerals, 6 (4) 283-296 doi:10.1180/claymin.1966.006.4.03DOI: 10.1180/claymin.1966.006.4.03
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hydrobiotite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hydrobiotite-1966},
  note      = {Accessed 2026-05-11}
}