Hydrokenoralstonite

2Al2F6(H2O)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Hkra
Discovered
1871
Also known as
  • AHF
  • Atroarite
  • Hydrokenoralstoniet
  • +3 more

Where it forms, where it's found

Type locality
Ivigtut Mine
  1. Ivigtut stock
  2. Arsuk Fjord
  3. Sermersooq
  4. Greenland

61.2061°, -48.1756°

64recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless · white
Streak
White
Tenacity
brittle
Cleavage
Imperfect/Fair

On (111).

Fracture
Irregular/Uneven
Density
2.56 g/cm³

Optical

Optical type
Isotropic
Surface relief
Low
Principal indices
n 1.399 – 1.427
Birefringence
Frequently exhibits weak anomalous birefringence, with the crystals divided into eight uniaxial (or biaxial) sectors, or otherwise.
Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.413

Crystallography

Crystal system
Isometric
Space group
#222
Cell parameters
a = 9.91(4) Å
Z
8
Morphology

Crystals octahedral, often with small (001); less often cubo-octahedral, or cubic with small (111).

Type-locality form

octahedral crystals to 1.5mm

Comment

SG Fd-3m. Atencio et al. (2017) give a = 9.8455(7) Å.

Crystal structure

Synonyms

  • AHF
  • Atroarite
  • Hydrokenoralstoniet
  • Ralstonit
  • Ralstonita
  • Ralstonite

In other languages

German
Hydrokenoralstonit
Italian
Hydrokenoralstonite, idrogenoralstonite · idrokenoralstonite

Classification

Strunz
10th ed.

3.CF.05

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CFTekto-aluminofluoridesGroup
  • 3.CF.05HydrokenoralstoniteSpecies
Dana
8th ed.

11.06.12.01

  • 11Halide ComplexesClass
  • 11.06Aluminofluorides - Isolated OctahedraType
  • 11.06.12— unnamed intermediate level —Group
  • 11.06.12.01HydrokenoralstoniteSpecies
CIM

8.6.9

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.6Halides of AlGroup
  • 8.6.9HydrokenoralstoniteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1871Brush, G.J. (1871) On ralstonite, a new fluoride from Arksut-Fiord. American Journal of Science and Arts: 102: 30-31.
  2. 1881Bertrand, E. (1881) Étude optique de différents minéraux. Bulletin de la Société française de Minéralogie: 4: 34-38.
  3. 1882Brandt, J. (1882) Ueber die chemische Zusammensetzung der Mineralien der Kryolithgruppe. Annalen der Chemie: 213: 1-14.
  4. 1886Penfield, S.L., Harper, D.N. (1886) On the chemical composition of ralstonite. American Journal of Science: 32: 380-385.
  5. 1891Brauns (1891) Die opt. Anom. der Kryst., Leipzig: 242.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hydrokenoralstonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hydrokenoralstonite-3354},
  note      = {Accessed 2026-05-11}
}