Illite

K0.65Al2.0[Al0.65Si3.35O10](OH)2
IMA symbol
Ilt
Discovered
1937
Also known as
  • Glimmerton
  • Hydromuscovite
  • Ilito
  • +5 more

Where it forms, where it's found

Geological setting

The Maquoketa shale, Gilead, Calhoun Co., Illinois, USA; and at Takova, Yugoslavia.

Found in a wide variety of environments, the materials of this series form by either weathering or hydrothermal alteration of muscovite-phengite; but some is authigenic or could be derived from alteration of K-feldspars or recrystallization of smectites. Common in sediments, clays, marls, shales and some slates. Interstratified illite-smectite converts to illite at depths and mixed-layer ratios have been used to interpret the depth of burial of sediments.

Type locality
Maquoketa Shale
  1. Gilead
  2. Calhoun County
  3. Illinois
  4. USA
1,944recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Gray-white to silvery-white · greenish-gray · sometimes stained other hues.
Streak
White
Tenacity
elastic
Cleavage
Perfect

Perfect on (001).

Fracture
Micaceous
Density
2.79 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 5 – 25° · 2V calc = 42 – 68°
Refractive index
1.535 – 1.605
Surface relief
Moderate
Principal indices
nα 1.535 – 1.57 · nβ 1.555 – 1.6 · nγ 1.565 – 1.605
Dispersion
none
UV response
Not fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0325
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]325 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation325 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#11
Cell parameters
a = 5.19 Å · b = 8.95 Å · c = 9.95 Å
Cell angles
β = 94.87 °
Ratio a:b:c
1 : 1.724 : 1.917
Z
2
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
49.87%
14SiSiliconSilicon3.3528.08594.085
24.44%
13AlAluminiumAluminium2.6526.98271.502
18.57%
19KPotassiumPotassium0.6539.09825.414
6.60%
1HHydrogenHydrogen21.0082.016
0.52%
Total385.005100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Glimmerton
  • Hydromuscovite
  • Ilito
  • Illiet
  • Illiit
  • Illit
  • Illita
  • Killinite

Classification

Dana
8th ed.

71.02.2d.02

  • 71Phyllosilicates Sheets of Six-membered RingsClass
  • 71.02Sheets of 6-membered rings with 2:1 layersType
  • 71.02.2d— unnamed intermediate level —Group
  • 71.02.2d.02IlliteSpecies

Literature, links & citation

Citations
  1. Gaudette, H.E. (196x) The Nature of Illite, Thirteenth Conference on Clay and Clay Minerals, p. 1-35.
  2. Self, Peter G. and Eggleton, Richard A. (2025): Tumut illite. Australian Journal of MIneralogy 26 (1), 63-69.
  3. Árkai, P.; Tóth, M.N. (1983): Illite crystallinity: combined effects of domain size and lattice distortion. Acta Geologica Hungarica, 26, 341-358.
  4. Kübler, B. (1990): "Cristallinité" de l'illite et mixed layers : brève revision. Schweiz. Miner. Petrogr. Mitt., 70, 89-93.
  5. 1937Grim, R. E., Bray, R. H., Bradley, and W. F. (1937) The mica in argillaceous sediments. American Mineralogist, 22 (7) 813-829
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Illite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/illite-2011},
  note      = {Accessed 2026-05-11}
}