Itoite

Pb3GeO2(SO4)2(OH)2
IMA status
  • Approved
IMA symbol
It
Discovered
1957
Also known as
  • Itoiet

Where it forms, where it's found

Geological setting

Oxidation zone of a germanium-bearing Cu, and As-rich polymetallic ore deposit

Type locality
Tsumeb Mine (Ongopolo Mine)
  1. Tsumeb
  2. Oshikoto Region
  3. Namibia

-19.2270°, 17.7276°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent
Colour
White
Streak
White
Tenacity
brittle
Density
6.67 g/cm³

Optical

Optical type
Biaxial
Surface relief
Very high
Principal indices
n 1.84 – 1.85
Birefringence
0.010
Pleochroism
Non-pleochroic
Dispersion
relatively strong
UV response
Not fluorescent in UV; fluoresces rose-violet in x-rays
Notes

Crystals are cloudy compared with transparent fleischerite. It is significant the the refractive indices of itoite are very very much higher than fleischerite. Type material from Harvard is supposedly a mixture of itoite and fleischerite (Carl Francis, pe

Michel-Lévy diagramhighlighted lineδ = 0.0100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]100 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation100 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pnma
Cell parameters
a = 8.47 Å · b = 5.38 Å · c = 6.94 Å
Ratio a:b:c
1 : 0.635 : 0.819
Z
4
Morphology

Acicular

Type-locality form

White acicular crystals

Comment

Analogous to anglesite

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead3207.200621.600
65.27%
8OOxygenOxygen1215.999191.988
20.16%
32GeGermaniumGermanium172.63072.630
7.63%
16SSulfurSulfur232.06064.120
6.73%
1HHydrogenHydrogen21.0082.016
0.21%
Total952.354100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Itoiet

In other languages

German
Itoit
Italian
Itoite
Japanese
伊藤石

Classification

Strunz
10th ed.

7.BD.50

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BDWith only large cationsGroup
  • 7.BD.50ItoiteSpecies
Dana
8th ed.

30.02.06.01

  • 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
  • 30.02(AB)2(XO4)ZqType
  • 30.02.06— unnamed intermediate level —Group
  • 30.02.06.01ItoiteSpecies
CIM

25.7.10

  • 25SulphatesClass
  • 25.7Sulphates of PbGroup
  • 25.7.10ItoiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1957Frondel, Clifford, Ito, Jun (1957) The geochemistry of germanium in the oxidized zone of the Tsumeb Mine, South West Africa. American Mineralogist, 42 (11-12) 743-753
  2. 1960Fleischer, M. (1960) New mineral names. American Mineralogist, 45 (11-12). 1313-1317
  3. 1960Frondel, Clifford, Strunz, Hugo (1960) Fleischerit und Itoite, zwei neue Germanium-Mineralien von Tsumeb. Neues Jahrbuch für Mineralogie - Monatshefte, 1960. 132-142
  4. 1975Otto, H.H. (1975) Die Kristallstruktur von Fleischerit, Pb3Ge[(OH)6|(SO4)2]•3H2O, sowie kristallchemische Untersuchungen an isotypen Verbindungen. Neues Jahrbuch für Mineralogie, Abhandlungen: 123: 160-190. (in German with English abs.)
  5. 2005(2005) Itoite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Itoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/itoite-2056},
  note      = {Accessed 2026-05-11}
}