Kaňkite

Fe3+(AsO4) · 3.5H2O
IMA status
  • Approved
IMA symbol
Kňk
Discovered
1976
Also known as
  • Kaňkiet

Where it forms, where it's found

Geological setting

An alteration product of arsenopyrite.

Type locality
Kaňk
  1. Kutná Hora
  2. Kutná Hora District
  3. Central Bohemian Region
  4. Czech Republic
35recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Yellowish green · paler greenish yellow on exposure to air · very pale grayish yellow to pale yellow in transmitted light
Streak
Grayish yellow
Fracture
Irregular/Uneven
Density
2.60 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.664 – 1.68
Surface relief
High
Principal indices
nα 1.664 · nγ 1.680
Dispersion
strong
Michel-Lévy diagramhighlighted lineδ = 0.0160
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]160 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation160 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P2
Cell parameters
a = 18.803(15) Å · b = 17.490(18) Å · c = 7.633(5) Å
Cell angles
β = 92.71(5) °
Ratio a:b:c
1 : 0.930 : 0.406
Z
16
Type-locality form

Yellowish-green botryoidal coatings and crusts to 7 mm thick.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen7.515.999119.993
46.54%
33AsArsenicArsenic174.92274.922
29.06%
26FeIronIron155.84555.845
21.66%
1HHydrogenHydrogen71.0087.056
2.74%
Total257.815100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Kaňkiet

In other languages

French
kaňkite
German
IMA 1975-005 · Kaňkit
Italian
Kaňkite

Classification

Strunz
10th ed.

8.CE.60

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CEWith only medium-sized cations, RO4:H2O about 1:2.5Group
  • 8.CE.60KaňkiteSpecies
Dana
8th ed.

40.05.04

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.05AXO4·xH2OType
  • 40.05.04Gainesite GroupGroup
  • 40.05.04KaňkiteSpecies
CIM

20.9.3

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.9Arsenates of FeGroup
  • 20.9.3KaňkiteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1976Cech, F., Jansa, J., Novák, F. (1976) Kankite, FeAsO4·3½H2O, a new mineral. Neues Jahrbuch für Mineralogie, Monatshefte: 1976: 426-436.
  2. 1977Fleischer, Michael, Cabri, Louis J., Nickel, Ernest H., Pabst, Adolf (1977) New Mineral Names. American Mineralogist, 62 (5-6) 593-600
  3. 1985Dunn, Pete J., Chao, George Y., Fleischer, Michael, Ferraiolo, James A., Langley, Richard H., Pabst, Adolf, Zilczer, Janet A. (1985) New mineral names. American Mineralogist, 70 (1-2) 214-221
  4. 2005(2005) Kaňkite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2016Majzlan, Juraj; Palatinus, Lukáš; Plášil, Jakub (2016) Crystal structure of Fe2(AsO4)(HAsO4)(OH)(H2O)3, a dehydration product of kaňkite. European Journal of Mineralogy, 28 (1). 63-70 doi:10.1127/ejm/2015/0027-2495DOI: 10.1127/ejm/2015/0027-2495
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kaňkite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kankite-2153},
  note      = {Accessed 2026-05-11}
}