Khmaralite

Mg4(Mg3Al9)O4[Si5Be2Al5O36]
IMA status
  • Approved
IMA symbol
Kma
Also known as
  • IMA1998-027
  • Khmaraliet
  • Khmaralit

Where it forms, where it's found

Geological setting

Pegmatite.

Type locality
"Zircon Point" pegmatite
  1. Khmara Bay
  2. Casey Bay
  3. Napier Complex
  4. Enderby Land
  5. East Antarctica
  6. Antarctica

-67.3741°, 49.0651°

3recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789107/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Translucent
Colour
Dark greenish blue to very dark green
Streak
Green-gray
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.61 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 34° · 2V calc = 28°
Refractive index
1.725 – 1.741
Surface relief
High
Principal indices
nα 1.725 · nβ 1.740 · nγ 1.741
Birefringence
0.016
Pleochroism
Strong

X = colorless or very light tan, Y = blue-green, and Z = deep blue-green.

Dispersion
r > v strong
Extinction
Y // b.
Notes

Very like sapphirine.

Michel-Lévy diagramhighlighted lineδ = 0.0160
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]160 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation160 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 18.8 Å · b = 14.371 Å · c = 11.254 Å
Cell angles
β = 125.53 °
Ratio a:b:c
1 : 0.764 : 0.599
Z
4
Morphology

Tablets flattened parallel to (010).

Type-locality form

Foliated aggregates nearly 3 cm across of parallel tablets. The tablets are flattened parallel to (010) and range from 1-7 mm across and from 0.5-4 mm thick.

Comment

Related to sapphirine-2M but with different cation ordering and doubled chain repeat.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4015.999639.960
47.53%
13AlAluminiumAluminium1426.982377.748
28.06%
12MgMagnesiumMagnesium724.305170.135
12.64%
14SiSiliconSilicon528.085140.425
10.43%
4BeBerylliumBeryllium29.01218.024
1.34%
Total1346.292100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1998-027
  • Khmaraliet
  • Khmaralit

In other languages

German
IMA 1998-027 · Khmaralith
Italian
Khmaralite

Classification

Strunz
10th ed.

9.DH.50

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DHInosilicates with 4-periodic single chains, Si4O12Group
  • 9.DH.50KhmaraliteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 1981Grew, Edward S. (1981) Surinamite, taaffeite, and beryllian sapphirine from pegmatites in granulite facies rocks of Casey Bay, Enderby Land, Antarctica. American Mineralogist, 66 (9-10) 1022-1033
  2. 1999Barbier, Jacques, Grew, Edward S., Moore, Paulus B., Su, Shu-Chun (1999) Khmaralite, a new beryllium-bearing mineral related to sapphirine; a superstructure resulting from partial ordering of Be, Al, and Si on tetrahedral sites. American Mineralogist, 84 (10) 1650-1660 doi:10.2138/am-1999-1020 DOI: 10.2138/am-1999-1020
  3. 2002Christy, A.G., Tabira, Y., Hölscher, A., Grew, E.S., Schreyer, W. (2002) Synthesis of beryllian sapphirine in the system MgO-BeO-Al2O3-SiO2-H2O and comparison with naturally occurring beryllian sapphirine and khmaralite. Part 1: Experiments, TEM, and XRD. American Mineralogist, 87 (8) 1104-1112 doi:10.2138/am-2002-8-907 DOI: 10.2138/am-2002-8-907
  4. 2004Christy, A.G., Grew, E.S. (2004) Synthesis of beryllian sapphirine in the system MgO-BeO-Al2O3-SiO2-H2O and comparison with naturally occurring beryllian sapphirine and khmaralite, Part 2: A chemographic study of Be content as a function of P, T, assemblage and FeMg–1 exchange. American Mineralogist, 89 (2-3). 327-338 doi:10.2138/am-2004-2-311DOI: 10.2138/am-2004-2-311
  5. 2021(2021) Khmaralite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Khmaralite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/khmaralite-7136},
  note      = {Accessed 2026-05-11}
}