Krautite

Mn(AsO3OH) · H2O
IMA status
  • Approved
IMA symbol
Kra
Discovered
1975
Also known as
  • IMA1974-028
  • Krautiet

Where it forms, where it's found

Type locality
Săcărâmb
  1. Certeju de Sus
  2. Hunedoara County
  3. Romania

45.9739°, 23.0400°

8recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Rose red · rose pink · to brownish red
Tenacity
brittle
Cleavage
Perfect

(010) perfect micaceous; (101) good, (101) poor.

Density
3.30 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 60 – 70° · 2V calc = 68°
Refractive index
1.62 – 1.686
Surface relief
High
Principal indices
nα 1.620 · nβ 1.639 · nγ 1.686
Birefringence
0.066
Pleochroism
Non-pleochroic
Dispersion
r < v strong
Extinction
Z ^<mi> {_101}</mi> = 16°; X = b; elongation (+).
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0660
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]660 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation660 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21
Cell parameters
a = 8.012(2) Å · b = 15.956(4) Å · c = 6.801(2) Å
Cell angles
β = 96.60(3) °
Ratio a:b:c
1 : 1.992 : 0.849
Z
8
Type-locality form

As thin lamellae, to 2 mm.

Comment

For synthetic crystal. Strong P21/n pseudosymmetry.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen515.99979.995
37.58%
33AsArsenicArsenic174.92274.922
35.19%
25MnManganeseManganese154.93854.938
25.81%
1HHydrogenHydrogen31.0083.024
1.42%
Total212.879100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1974-028
  • Krautiet

In other languages

French
Krautite
German
IMA 1974-028 · Krautit
Italian
Krautite

Classification

Strunz
10th ed.

8.CB.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CBWith only medium-sized cations, RO4:H2O = 1:1Group
  • 8.CB.15KrautiteSpecies
Dana
8th ed.

39.01.03.01

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.01A[HXO4]·xH2OType
  • 39.01.03— unnamed intermediate level —Group
  • 39.01.03.01KrautiteSpecies
CIM

20.8.7

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.8Arsenates of MnGroup
  • 20.8.7KrautiteSpecies

Group, growth & confusion

In the same group
1 members

Literature, links & citation

Citations
  1. 1975Fontan, François, Orliac, Marcel, Permingeat, François (1975) La krautite MnHAsO4 • H2O, une nouvelle espèce minérale. Bulletin de Minéralogie, 98 (1) 78-84 doi:10.3406/bulmi.1975.6961 DOI: 10.3406/bulmi.1975.6961
  2. 1979Catti, Michele, Franchini-Angela, Marinella (1979) Krautite, Mn(H2O)(AsO3OH): crystal structure, hydrogen bonding and relations with haidingerite and pharmacolite. American Mineralogist, 64 (11-12) 1248-1254
  3. 1981Beneke, Klaus; Lagaly, Gerhard (1981) Krautite, MnHAsO4 · H2O - an intracrystalline reactive mineral. American Mineralogist, 66 (3-4). 432-435
  4. 1990Buckley, A. M., Bramwell, S. T., Day, P. (1990) Intercalation reactions of krautite, HMnAsO4-H2O. American Mineralogist, 75 (9-10) 1140-1146
  5. 2005(2005) Krautite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Krautite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/krautite-2272},
  note      = {Accessed 2026-05-11}
}