Laphamite

As2Se3
IMA status
  • Approved
IMA symbol
Lpm
Discovered
1985
IMA approved
1985
Also known as
  • IMA1985-021
  • Laphamiet

Where it forms, where it's found

Geological setting

Secondary mineral formed, probably by sublimation, on a clinker adjacent to a surface vent on a burning pile of coal.

Type locality
Burnside
  1. Northumberland County
  2. Pennsylvania
  3. USA

40.7667°, -76.5583°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Dark red
Streak
Red-orange
Tenacity
malleable
Cleavage
Perfect

On (010)

Density
4.5 g/cm³

Optical

Pleochroism
Not Visible
Anisotropism
Moderate with grey rotation tints.
Bireflectance
Moderate, white to grey.
Internal reflections
Fiery red; also golden yellow along scratches.
Tropism
Anisotropic
Reflectance R%
(34.4,42.1,19.6,26.2) 400, (33.9,41.0,18.8,25.1) 420, (33.8,39.9,18.7,24.0) 440, (33.8,38.8,18.5,22.8) 460, (33.3,37.5,17.9,21.5) 480, (32.3,36.3,17.0,20.4) 500, (30.9,35.1,15.8,19.3) 520, (29.5,34.0,14.6,18.3) 540, (28.4,33.1,13.6,17.5) 560, (27.6,32.3,13.0,16.8) 580, (26.9,31.6,12.4,16.3) 600, (26.4,31.1,12.1,15.9) 620, (26.4,30.9,12.3,15.9) 640, (26.3,30.6,12.5,15.9) 660, (26.1,30.4,12.4,15.8) 680, (25.9,30.1,12.3,15.8) 700

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 11.86(1) Å · b = 9.756(9) Å · c = 4.265(9) Å
Cell angles
β = 90.17(30) °
Ratio a:b:c
1 : 0.823 : 0.360
Unit cell volume
493.5 ų
Z
4
Morphology

Crystals are tabular on (010), elongate on [100], and are composed of the forms (100), {1l0}, (101), and (301).

Type-locality form

Dark red euhedral crystals, to 5.0 mm.

Comment

P21/n

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
34SeSeleniumSelenium378.971236.913
61.26%
33AsArsenicArsenic274.922149.844
38.74%
Total386.757100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1985-021
  • Laphamiet

In other languages

German
IMA 1985-021 · Laphamit
Italian
Lafamite · Laphamite
Russian
лафамит

Classification

Strunz
10th ed.

2.FA.30

  • 2Sulfides and SulfosaltsClass
  • 2.FSulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2ODivision
  • 2.FAWith As, (Sb), SGroup
  • 2.FA.30LaphamiteSpecies
Dana
8th ed.

02.11.06.01

  • 02SulfidesClass
  • 02.11AmBnXp, with (m+n):p = 2:3Type
  • 02.11.06— unnamed intermediate level —Group
  • 02.11.06.01LaphamiteSpecies
CIM

3.7.10

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.7Sulphides etc. of V, As, Sb and BiGroup
  • 3.7.10LaphamiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1968Kirkinskii, V.A., Yakushev, V.G. (1968) A new polymorphic modification of arsenic selenide obtained at high pressures (in English). Doklady Chemistry: 182: 896-898.
  2. 1968Kirkinskii, V.A., Yakushev, V.G. (1968) A new polymorphic modification of arsenic selenide obtained at high pressures (in Russian). Doklady Akademii Nauk SSSR: 182: 1083-1086.
  3. 1970Kirkinskii, V.A., Ryaposov, A.P., Yakushev, V.G. (1970) Synthesis of a third polymorphic modification of arsenic selenide at high pressure. Soviet Physics Solid State, USSR: 11: 1923-1924.
  4. 1971Zallen, R., Slade, M.L., Ward, A.T. (1971) Lattice vibrations and interlayer interactions in crystalline As2S3 and As2Se3. Physical Review B: 3: 4257-4273.
  5. 1985Stergiou, A. C., Rentzeperis, P. J. (1985) The crystal structure of arsenic selenide, As2Se3. Zeitschrift für Kristallographie - Crystalline Materials, 173 (3) 185-191 doi:10.1524/zkri.1985.173.3-4.185 DOI: 10.1524/zkri.1985.173.3-4.185
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Laphamite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/laphamite-2328},
  note      = {Accessed 2026-05-11}
}