Macphersonite

Pb4(SO4)(CO3)2(OH)2
IMA status
  • Approved
IMA symbol
Mps
Discovered
1984
Also known as
  • IMA1982-105
  • Macphersoniet

Where it forms, where it's found

Geological setting

Oxidation zone of lead deposits.

Type locality
Susanna Mine (Glennery Scar vein
  1. Susanna vein [Scar vein]
  2. Portobello vein
  3. Humby vein
  4. Lead vein)
  5. Leadhills
  6. South Lanarkshire
  7. Scotland
  8. UK

55.4233°, -3.7675°

8recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colorless · white · very pale amber
Cleavage
Perfect

(010)

Fracture
Irregular/Uneven
Density
6.50 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 35 – 36° · 2V calc = 28°
Refractive index
1.87 – 2.01
Surface relief
Very high
Principal indices
nα 1.87 · nβ 2 · nγ 2.01
Dispersion
r > v
UV response
May exhibit a bright yellow fluorescence under SW UV and LW UV.
Michel-Lévy diagramhighlighted lineδ = 0.1400
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1400 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1400 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 10.383(2) Å · b = 23.050(5) Å · c = 9.242(2) Å
Ratio a:b:c
1 : 2.220 : 0.890
Unit cell volume
2211.87 ų
Z
8
Morphology

Pseudo-hexagonal, tabular to micaceous crystals.

Twinning

Common. Lamellar and contact, composition plane (102).

Type-locality form

A composite crystal (2 x 3 x 7 mm) displaying interpenetrant growth (Leadhills). Abundant pseudo hexagonal, tabular to micaceous crystals, 2-5 mm (Argentolle Mine).

Comment

Space Group: P cab

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead4207.200828.800
76.82%
8OOxygenOxygen1215.999191.988
17.79%
16SSulfurSulfur132.06032.060
2.97%
6CCarbonCarbon212.01124.022
2.23%
1HHydrogenHydrogen21.0082.016
0.19%
Total1078.886100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1982-105
  • Macphersoniet

In other languages

German
IMA 1982-105 · Macphersonit
Italian
Macphersonite

Classification

Strunz
10th ed.

5.BF.40

  • 5CarbonatesClass
  • 5.BCarbonates with additional anions, without H2ODivision
  • 5.BFWith (Cl), SO4, PO4, TeO3Group
  • 5.BF.40MacphersoniteSpecies
Dana
8th ed.

17.01.04.01

  • 17Compound CarbonatesClass
  • 17.01MiscellaneousType
  • 17.01.04— unnamed intermediate level —Group
  • 17.01.04.01MacphersoniteSpecies
CIM

12.2.12

  • 12Carbonates with other anionsClass
  • 12.2Carbonates with sulphateGroup
  • 12.2.12MacphersoniteSpecies

Group, growth & confusion

Often grow together
1 mineral
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1984Livingstone, A., Sarp, H. (1984) Macphersonite, a new mineral from Leadhills, Scotland, and Saint-Prix, France— a polymorph of leadhillite and susannite. Mineralogical Magazine, 48 (347) 277-282 doi:10.1180/minmag.1984.048.347.14 DOI: 10.1180/minmag.1984.048.347.14
  2. 1985Dunn, Pete J., Fleischer, Michael, Langley, Richard H., Shigley, James E., Zilczer, Janet A. (1985) New mineral names. American Mineralogist, 70 (7-8) 871-881
  3. 1998Steele, Ian M., Pluth, Joseph J., Livingstone, Alec (1998) Crystal structure of macphersonite (Pb4SO4(CO3)2(OH)2): comparison with leadhillite. Mineralogical Magazine, 62 (4) 451-459 doi:10.1180/002646198547828 DOI: 10.1180/002646198547828
  4. 2005(2005) Macphersonite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Macphersonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/macphersonite-2513},
  note      = {Accessed 2026-05-11}
}