Leadhillite

Pb4(SO4)(CO3)2(OH)2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Lhi
Discovered
1832
Also known as
  • Bleisulphotricarbonat
  • Lead sulphato-tricarbonate
  • Leadillita
  • +8 more

Where it forms, where it's found

Geological setting

Leadhillite is a secondary mineral found in the oxidized zones of lead mineral deposits.

Type locality
Susanna Mine (Glennery Scar vein
  1. Susanna vein [Scar vein]
  2. Portobello vein
  3. Humby vein
  4. Lead vein)
  5. Leadhills
  6. South Lanarkshire
  7. Scotland
  8. UK

55.4233°, -3.7675°

286recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Resinous to adamantine
Transparency
Transparent · Translucent
Colour
Colourless to white · grey · yellowish · pale green to blue · colourless in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
Perfect

Perfect on (001) and easy.

Fracture
Irregular/Uneven
Density
6.55 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 10° · 2V calc = 10°
Refractive index
1.87 – 2.01
Surface relief
Very high
Principal indices
nα 1.87 · nβ 2.0085 · nγ 2.01
Dispersion
relatively strong
UV response
Pale yellowish under (SW UV).
Michel-Lévy diagramhighlighted lineδ = 0.1400
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1400 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1400 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 9.11 Å · b = 20.82 Å · c = 11.59 Å
Cell angles
β = 90.46 °
Ratio a:b:c
1 : 2.285 : 1.272
Unit cell volume
2198.21 ų
Z
8
Morphology

Usually as thin to thick tabular pseudohexagonal crystals, (001) with hexagonal outline; several rhombohedral and pyramidal forms common; also prismatic parallel to [001], or equant or granular. When [101] is developed the faces may show striations, or be curved.

Twinning

Commonly twinned on (140); as lamellar twins with the composition plane parallel to (142) or (340); as aragonite-type contact twins; as penetration twins; with other twin laws producing pseudohexagonal groupings.

Parting
Translation gliding on (001), as well as twin gliding with K1(340), σ2[140]; K2(34¯0), σ1[140].
Comment

Pseudohexagonal.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead4207.200828.800
76.82%
8OOxygenOxygen1215.999191.988
17.79%
16SSulfurSulfur132.06032.060
2.97%
6CCarbonCarbon212.01124.022
2.23%
1HHydrogenHydrogen21.0082.016
0.19%
Total1078.886100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bleisulphotricarbonat
  • Lead sulphato-tricarbonate
  • Leadillita
  • Maxit
  • Maxita
  • Maxite
  • Plomb carbonaté rhomboidal
  • Plomb sulfato-tricarbonaté
  • Psimythit
  • Schwefelkohlensaures Blei
  • Ternärbleierz

In other languages

French
Leadhillite
German
Leadhillit
Spanish
leadhillita
Italian
leadhillite
Arabic
ليدهيليت

Classification

Strunz
10th ed.

5.BF.40

  • 5CarbonatesClass
  • 5.BCarbonates with additional anions, without H2ODivision
  • 5.BFWith (Cl), SO4, PO4, TeO3Group
  • 5.BF.40LeadhilliteSpecies
Dana
8th ed.

17.01.02.01

  • 17Compound CarbonatesClass
  • 17.01MiscellaneousType
  • 17.01.02— unnamed intermediate level —Group
  • 17.01.02.01LeadhilliteSpecies
CIM

12.2.11

  • 12Carbonates with other anionsClass
  • 12.2Carbonates with sulphateGroup
  • 12.2.11LeadhilliteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. Maxit. - Journal für Praktische Chemie 5(1):470-476; Weinheim. (as Maxite)
  2. 1817Bournon, Comte de (1817) Catalogue de la collection minéralogique particulière du roi, with atlas in fol., Paris: 343. (as Plomb carbonaté rhomboidal)
  3. 1820Brooke (1820) Edinburgh Philosophical Journal, Edinburgh: 3: 117 (as Sulphato-tricarbonate of Lead).
  4. 1832Beudant, François-Sulpice (1832) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 2 - Tome II [Volume II]. Chez Verdière.
  5. 1847Dufrénoy, A. (1847) Traité de minéralogie, 1st. Edition, Vol. 3: 152 (as Plomb sulfato-tricarbonaté).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Leadhillite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/leadhillite-2361},
  note      = {Accessed 2026-05-11}
}