Mandarinoite

Fe3+2(Se4+O3)3 · 6H2O
IMA status
  • Approved
IMA symbol
Mda
Discovered
1978
Also known as
  • IMA1977-049
  • Mandarinoiet

Where it forms, where it's found

Geological setting

Formed by the oxidation of penroseite and pyrite.

Type locality
Virgen de Surumi mine
  1. Pakajake Canyon
  2. Colquechaca Municipality
  3. Chayanta Province
  4. Potosí
  5. Bolivia

-18.6500°, -66.0167°

18recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · greasy
Transparency
Transparent
Colour
Pale yellow green

Almost colorless in oil immersion or in thin section.

Streak
Very pale green
Cleavage
None Observed
Density
2.93 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 80 – 85° · 2V calc = 80°
Refractive index
1.715 – 1.87
Surface relief
High
Principal indices
nα 1.715 · nβ 1.797 – 1.8 · nγ 1.86 – 1.87
Pleochroism
Visible

X = colorless; Y = Z = pale green.

Dispersion
strong; type description says none
UV response
Not fluorescent.
Notes

X = b; Z ∧ c = 2(1)° in the acute angle between a and c.

Michel-Lévy diagramhighlighted lineδ = 0.1500
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1500 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1500 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 16.81(4) Å · b = 7.88(2) Å · c = 10.019(2) Å
Cell angles
β = 98.26(2) °
Ratio a:b:c
1 : 0.469 : 0.596
Z
4
Morphology

Crystals are swordlike, in rosettes and subparallel aggregates. Elongate along [001} and flattened parallel to (110). Forms observed include (100), (110), (011) and (101).

Twinning

Common as contact twins on (100).

Parting
Parting on (100)
Type-locality form

Crystals to 0.5 mm in groups.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1515.999239.985
39.95%
34SeSeleniumSelenium378.971236.913
39.44%
26FeIronIron255.845111.690
18.60%
1HHydrogenHydrogen121.00812.096
2.01%
Total600.684100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1977-049
  • Mandarinoiet

In other languages

German
IMA 1977-049 · Mandarinoit
Italian
Mandarinoite

Classification

Strunz
10th ed.

4.JH.15

  • 4OxidesClass
  • 4.JArsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodatesDivision
  • 4.JHSelenites without additional anions, with H2OGroup
  • 4.JH.15MandarinoiteSpecies
Dana
8th ed.

34.03.04.01

  • 34Selenites, Tellurites and SulfitesClass
  • 34.03A2(XO3)3·xH2OType
  • 34.03.04— unnamed intermediate level —Group
  • 34.03.04.01MandarinoiteSpecies
CIM

28.1.11

  • 28Selenites, Selenates, Tellurites, and TelluratesClass
  • 28.1SelenitesGroup
  • 28.1.11MandarinoiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1978Dunn, P. J., Peacor, D. R., Sturman, B. D. (1978) Mandarinoite, a new ferric-iron selenite from Bolivia. The Canadian Mineralogist, 16 (4) 605-609
  2. 1984Hawthorne, Frank C. (1984) The crystal structure of mandarinoite, Fe3+2Se3O9 · 6H2O. The Canadian Mineralogist, 22 (3) 475-480
  3. 2005(2005) Mandarinoite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2018Holzheid, Astrid, Charykova, Marina V., Krivovichev, Vladimir G., Ledwig, Brendan, Fokina, Elena L., Poroshina, Ksenia L., Platonova, Natalia V., Gurzhiy, Vladislav V. (2018) Thermal behavior of ferric selenite hydrates (Fe2(SeO3)3·3H2O, Fe2(SeO3)3·5H2O) and the water content in the natural ferric selenite mandarinoite. Geochemistry, 78 (2) 228-240 doi:10.1016/j.chemer.2018.01.002DOI: 10.1016/j.chemer.2018.01.002
  5. 2018Lelet, Maxim I.; Charykova, Marina V.; Holzheid, Astrid; Ledwig, Brendan; Krivovichev, Vladimir G.; Suleimanov, Evgeny V. (2018) A Calorimetric and Thermodynamic Investigation of the Synthetic Analogue of Mandarinoite, Fe2(SeO3)3·5H2O. Geosciences, 8 (11). 391 doi:10.3390/geosciences8110391 DOI: 10.3390/geosciences8110391
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mandarinoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mandarinoite-2561},
  note      = {Accessed 2026-05-11}
}