Where it forms, where it's found
- Geological setting
Formed by the oxidation of penroseite and pyrite.
- Type locality
- Virgen de Surumi mine
- Pakajake Canyon
- Colquechaca Municipality
- Chayanta Province
- Potosí
- Bolivia
-18.6500°, -66.0167°
Safety & handling
Physical
Optical
- Optical type
- Biaxial (-) · 2V measured = 80 – 85° · 2V calc = 80°
- Refractive index
- 1.715 – 1.87
- Surface relief
- High
- Principal indices
- nα 1.715 · nβ 1.797 – 1.8 · nγ 1.86 – 1.87
- Pleochroism
- Visible
X = colorless; Y = Z = pale green.
- Dispersion
- strong; type description says none
- UV response
- Not fluorescent.
- Notes
X = b; Z ∧ c = 2(1)° in the acute angle between a and c.
Crystallography
- Space group
- #14
- Cell parameters
- a = 16.81(4) Å · b = 7.88(2) Å · c = 10.019(2) Å
- Cell angles
- β = 98.26(2) °
- Ratio a:b:c
- 1 : 0.469 : 0.596
- Z
- 4
- Morphology
Crystals are swordlike, in rosettes and subparallel aggregates. Elongate along [001} and flattened parallel to (110). Forms observed include (100), (110), (011) and (01).
- Twinning
Common as contact twins on (100).
- Parting
- Parting on (100)
- Type-locality form
Crystals to 0.5 mm in groups.
Chemical composition
Synonyms
- IMA1977-049
- Mandarinoiet
In other languages
- German
- IMA 1977-049 · Mandarinoit
- Italian
- Mandarinoite
Classification
4.JH.15
- 4OxidesClass
- 4.JArsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodatesDivision
- 4.JHSelenites without additional anions, with H2OGroup
- 4.JH.15MandarinoiteSpecies
34.03.04.01
- 34Selenites, Tellurites and SulfitesClass
- 34.03A2(XO3)3·xH2OType
- 34.03.04— unnamed intermediate level —Group
- 34.03.04.01MandarinoiteSpecies
28.1.11
- 28Selenites, Selenates, Tellurites, and TelluratesClass
- 28.1SelenitesGroup
- 28.1.11MandarinoiteSpecies
Group, growth & confusion
Literature, links & citation
- 1978Dunn, P. J., Peacor, D. R., Sturman, B. D. (1978) Mandarinoite, a new ferric-iron selenite from Bolivia. The Canadian Mineralogist, 16 (4) 605-609
- 1984Hawthorne, Frank C. (1984) The crystal structure of mandarinoite, Fe3+2Se3O9 · 6H2O. The Canadian Mineralogist, 22 (3) 475-480
- 2005(2005) Mandarinoite. Handbook of Mineralogy. Mineralogical Society of America
- 2018Holzheid, Astrid, Charykova, Marina V., Krivovichev, Vladimir G., Ledwig, Brendan, Fokina, Elena L., Poroshina, Ksenia L., Platonova, Natalia V., Gurzhiy, Vladislav V. (2018) Thermal behavior of ferric selenite hydrates (Fe2(SeO3)3·3H2O, Fe2(SeO3)3·5H2O) and the water content in the natural ferric selenite mandarinoite. Geochemistry, 78 (2) 228-240 doi:10.1016/j.chemer.2018.01.002DOI: 10.1016/j.chemer.2018.01.002
- 2018Lelet, Maxim I.; Charykova, Marina V.; Holzheid, Astrid; Ledwig, Brendan; Krivovichev, Vladimir G.; Suleimanov, Evgeny V. (2018) A Calorimetric and Thermodynamic Investigation of the Synthetic Analogue of Mandarinoite, Fe2(SeO3)3·5H2O. Geosciences, 8 (11). 391 doi:10.3390/geosciences8110391 DOI: 10.3390/geosciences8110391
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Mandarinoite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/mandarinoite-2561},
note = {Accessed 2026-05-11}
}