Matildite

AgBiS2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mtd
Discovered
1883
Also known as
  • Argentobismutit
  • Argentobismutita
  • Argentobismutite
  • +6 more

Where it forms, where it's found

Type locality
Matilda Mine
  1. Morococha District
  2. Yauli Province
  3. Junín
  4. Peru
302recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Iron-black to gray
Streak
Light gray
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
6.9 g/cm³

Optical

Pleochroism
Weak
Optical colour
White
Anisotropism
Weak
Tropism
Anisotropic
Reflectance R%
(41.4,47.2) 400, (41.9,47.8) 420, (42.2,48.3) 440, (43.1,48.8) 460, (43.4,49.3) 480, (43.4,49.3) 500, (43.0,49.0) 520, (42.8,48.4) 540, (42.5,47.8) 560, (42.2,47.3) 580, (41.7,46.9) 600, (41.3,46.7) 620, (40.8,46.7) 640, (40.3,46.7) 660, (39.9,46.3) 680, (39.3,46.1) 700
Reflected-light panel
41.8 %anisotropic · dual curve
Specimen sRGB 228, 162, 90
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Weak
Reflected colour
White

Crystallography

Crystal system
Trigonal
Space group
#89
Cell parameters
a = 4.0675(3) Å · c = 18.9570(13) Å
Morphology

Rarely as indistinct prismatic crystals, striated [001]. Massive, granular.

Comment

Space group and cell from Kolitsch et al. (2021). Originally assumed to have space group P-3m1. Note: Harris & Thorpe (1969) suggested a hexagonal cell with a = 8.12, c = 19.02 Å.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth1208.980208.980
54.86%
47AgSilverSilver1107.868107.868
28.31%
16SSulfurSulfur232.06064.120
16.83%
Total380.968100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Argentobismutit
  • Argentobismutita
  • Argentobismutite
  • Matildiet
  • Morocochite
  • Peruvite
  • Plenargyrite
  • Wismuthbleierz
  • Wismutisches Silber

In other languages

German
Matildit
Spanish
Matildita
Italian
Matildite

Classification

Strunz
10th ed.

2.JA.20

  • 2Sulfides and SulfosaltsClass
  • 2.JSulfosalts of PbS archetypeDivision
  • 2.JAGalena derivatives with little or no PbGroup
  • 2.JA.20MatilditeSpecies
Dana
8th ed.

03.07.01.01

  • 03SulfosaltsClass
  • 03.07ø = 2Type
  • 03.07.01Matildite GroupGroup
  • 03.07.01.01MatilditeSpecies
CIM

5.2.17

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.2Sulpharsenites etc. of AgGroup
  • 5.2.17MatilditeSpecies

Group, growth & confusion

In the same group
2 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. Kolitsch, Topa, D., Giester, G. (2021): Revisions of the crystal structures of matildite, AgBiS2, and christite, TlHgAsS3. Poster, MinPet 2021, Vienna, Austria, September 19-21, 2021; abstract in Mitt. Österr. Mineral. Ges. 167, 118.
  2. 1877Rammelsberg (1877) Zs. deutsche geol. Ges.: 29: 80.
  3. 1882Sandberger (1882): 1: 96 (as plenargyrite).
  4. 1883D'Achiardi, A. (1883) Matildite e scirmerite. I Metalli Loro Minerali e Miniere, Volume 1, Ulrico Hoepli (Milano): 136-137.
  5. 1886Genth, F.A. (1886) Contributions from the Laboratory of the University of Pennsylvania, No. 24. Proceedings of the American Philosophical Society: 23: 30-47. (as argentobismutite)
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Matildite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/matildite-2592},
  note      = {Accessed 2026-05-11}
}