Metathénardite

Na2(SO4)
IMA status
  • Approved
IMA symbol
Mthn
Discovered
1905
IMA approved
2016
Also known as
  • IMA2015-102
  • Metathénardiet

Where it forms, where it's found

Geological setting

Volcanic fumaroles.

Type locality
Yadovitaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.8333°, 160.3333°

7recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless · white · light-blue · greenish · yellowish · grayish or brownish
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
2.72 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.486 – 1.489
Surface relief
Low
Principal indices
nω 1.489 · nε 1.486
Pleochroism
Non-pleochroic
Michel-Lévy diagramhighlighted lineδ = 0.0030
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]30 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation30 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
P63/mmc
Cell parameters
a = 5.3467(9) Å · c = 7.088(2) Å
Z
2
Morphology

Hexagonal tabular to lamellar. Pinacoid (001) (usually the major form), with the hexagonal prism (100), the hexagonal dipyramid (102) and narrow faces of the hexagonal dipyramid (201).

Parting
None observed
Type-locality form

Hexagonal tabular, lamellar, or dipyramidal crystals (forms: (001), (100), (102), and (201)) up to 3 mm combined in crusts up to several hundred cm2 in area.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
45.06%
11NaSodiumSodium222.99045.980
32.37%
16SSulfurSulfur132.06032.060
22.57%
Total142.036100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2015-102
  • Metathénardiet

In other languages

German
IMA 2015-102 · Metathénardit

Classification

Strunz
10th ed.

7.AD.30

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.ADWith only large cationsGroup
  • 7.AD.30MetathénarditeSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1905Lacroix (1905) Bulletin de la Société française de Minéralogie: 23: 65.
  2. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  3. 2016(2016)
  4. 2016(2016)
  5. 2016Hålenius, U., Hatert, F., Pasero, M., Mills, S.J. (2016) New minerals and nomenclature modifications approved in 2016, CNMNC Newsletter no 30. Mineralogical Magazine, 80 (2) 407-413 doi:10.1180/minmag.2016.080.081DOI: 10.1180/minmag.2016.080.081
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Metathénardite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/metathenardite-30808},
  note      = {Accessed 2026-05-11}
}