Thénardite

Na2(SO4)
IMA status
  • Approved
IMA symbol
Thn
Discovered
1826
Also known as
  • Anhydrisches Natronsulfat
  • Pyrotechnite

Where it forms, where it's found

Geological setting

Salt lake.

Lakes and playas in arid regions; as efflorescences on soils in arid areas, and in caliche. Also occurs around volcanic fumaroles mixed with alkali halides and sulphates and as an incrustation on recent lavas.

Type locality
Espartinas Saltworks
  1. Ciempozuelos
  2. Community of Madrid
  3. Spain
288recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless · very light grey · light brown · colourless in transmitted light
Streak
White
Tenacity
brittle
Cleavage
Perfect

On (010) perfect; on (101) fair; on (100) incomplete

Fracture
Irregular/Uneven · Hackly
Density
2.664 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 83° · 2V calc = 86°
Refractive index
1.471 – 1.484
Surface relief
Low
Principal indices
nα 1.471 · nβ 1.477 · nγ 1.484
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0130
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]130 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation130 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#53
Cell parameters
a = 5.86 Å · b = 12.3 Å · c = 9.82 Å
Ratio a:b:c
1 : 2.099 : 1.676
Z
8
Morphology

Crystals dipyramidal (111) with minor truncations; tabular (010) rough and striated, and (101) present as large faces; prismatic [100], rare. Pulverulent crusts, efflorescences.

Twinning

On (110) common, yielding cruciform groups. Also on (011), yielding twins rather similar to gypsum "butterfly" twins.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
45.06%
11NaSodiumSodium222.99045.980
32.37%
16SSulfurSulfur132.06032.060
22.57%
Total142.036100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Anhydrisches Natronsulfat
  • Pyrotechnite

In other languages

French
Pyrotechnite · Thénardite
German
Thénardit
Spanish
Thenardita
Italian
thénardite
Chinese
無水芒硝
Russian
Тенардит
Arabic
تينارديت

Classification

Strunz
10th ed.

7.AD.25

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.ADWith only large cationsGroup
  • 7.AD.25ThénarditeSpecies
Dana
8th ed.

28.02.03.01

  • 28Anhydrous Acid and Normal SulfatesClass
  • 28.02A2XO4Type
  • 28.02.03— unnamed intermediate level —Group
  • 28.02.03.01ThénarditeSpecies
CIM

25.1.1

  • 25SulphatesClass
  • 25.1Sulphates of the alkali metals and ammoniumGroup
  • 25.1.1ThénarditeSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1826Casaseca, J.L. (1826) Analyse d'une nouvelle Substance minérale (la Thenardite). Annales de chimie et de physique: 32: 308-316.
  2. 1826Casaseca, J.L. (1826) Thenardite. The Annals of Philosophy: 12: 312-314.
  3. 1832Breithaupt, A. (1832) Vollständige Characteristik etc., 2nd. Ed.: 33 (as Anhydrisches Natronsulfat).
  4. 1855Scacchi (1855) Mem. Incend. Vesuvius, Naples (as Pyrotechnite).
  5. 1857Des Cloizeaux (1857) Annales des mines: 11: 318.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Thénardite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/thenardite-3935},
  note      = {Accessed 2026-05-11}
}