Metavoltine

K2Na6Fe2+Fe3+6O2(SO4)12 · 18H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mvt
Discovered
1883
Also known as

Where it forms, where it's found

Geological setting

Alteration product of pyrite in arid climates, fumaroles, and post mining oxidation product.

Type locality
Zagh Mine
  1. Hajjiabad
  2. Hajjiabad County
  3. Hormozgan Province
  4. Iran
89recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Yellowish brown · orange-brown · greenish brown
Cleavage
Perfect

Perfect on (0001).

Density
2.51 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.573 – 1.595
Surface relief
Moderate
Principal indices
nω 1.588 – 1.595 · nε 1.573 – 1.581
Pleochroism
Visible

Dichroic: La Compania material: O = Dark yellow, E = pale yellow Chuquicamata material: O = Brown. E = Light greenish yellow Chilean material (not specified): O = Dark yellow, E = Light yellow Peruvian material (not specified): O = Deep or

Michel-Lévy diagramhighlighted lineδ = 0.0145
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]145 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation145 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Cell parameters
a = 9.575(5) Å · c = 18.17(1) Å
Z
1
Morphology

Crystals tabular (0001) with a hexagonal outline. Commonly tiny. As granular or scaly aggregates.

Comment

May be 3 or _3

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen6815.9991087.932
51.41%
26FeIronIron755.845390.915
18.47%
16SSulfurSulfur1232.060384.720
18.18%
11NaSodiumSodium622.990137.940
6.52%
19KPotassiumPotassium239.09878.196
3.70%
1HHydrogenHydrogen361.00836.288
1.72%
Total2115.991100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Mausit
  • Mausita
  • Mausite
  • Metavoltaite
  • α-Metavoltine

In other languages

German
Metavoltin
Italian
Metavoltina · Metavoltine

Classification

Strunz
10th ed.

7.DF.35

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DFWith large and medium-sized cationsGroup
  • 7.DF.35MetavoltineSpecies
Dana
8th ed.

29.04.06.01

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.04AmBn(XO4)p·xH2O, with (m+n):p < 3:2 and > 1:1Type
  • 29.04.06— unnamed intermediate level —Group
  • 29.04.06.01MetavoltineSpecies
CIM

25.11.12

  • 25SulphatesClass
  • 25.11Sulphates of Fe and other metalsGroup
  • 25.11.12MetavoltineSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1883Blaas, J. (1883) Beiträge zur Kenntniss natürlicher wasserhaltiger Doppelsulfate. Sitzungsberichte der Mathematisch-Naturwissenschaftlichen Classe der Kaiserlichen Akademie der Wissenschaften, 87, 141-163.
  2. 1906Zambonini, F. (1906) Notizie mineralogiche sull'eruzione vesuviana dell'Aprile 1906. Accad. Sci. Fis. Mat. Napoli. Mem. 13, ser 2, 18–22.
  3. 1907Lacroix, Alfred (1907) Sur deux gisements nouveaux de métavoltite. Bulletin de Minéralogie, 30 (2) 30-36 doi:10.3406/bulmi.1907.2798DOI: 10.3406/bulmi.1907.2798
  4. 1908Zambonini (1908) Reale accademia delle scienze fisische e matematiche, Naples, Rendu: 158.
  5. 1911Aquilar (1911) Bollettino della Societa dei Naturalisti in Napoli: 25: 28.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Metavoltine — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/metavoltine-2696},
  note      = {Accessed 2026-05-11}
}