Nagashimalite

Ba4(V3+,Ti)4(O,OH)2[B2Si8O27]Cl
IMA status
  • Approved
IMA symbol
Ngs
Discovered
1980
Also known as
  • IMA1977-045
  • Nagashimaliet
  • Nagashimalit

Where it forms, where it's found

Geological setting

Manganese deposit in bedded chert.

Type locality
Mogurazawa mine
  1. Kiryu City
  2. Gunma Prefecture
  3. Japan

36.4397°, 139.3831°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Sub-metallic · Vitreous
Transparency
Transparent · Translucent · Opaque
Colour
Greenish-black
Streak
Green
Cleavage
None Observed
Density
4.08 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 30° · 2V calc = 38°
Refractive index
1.75 – 1.78
Surface relief
High
Principal indices
nα 1.75 · nβ 1.753 · nγ 1.78
Pleochroism
Strong

X = greenish-yellow; Y = green; Z = greenish-brown.

Dispersion
r > v, strong
Extinction
X = a; Y = c; Z = b.
Notes

Absorption: Z > Y > X.

Michel-Lévy diagramhighlighted lineδ = 0.0300
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]300 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation300 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#69
Cell parameters
a = 13.937(3) Å · b = 12.122(3) Å · c = 7.116(2) Å
Ratio a:b:c
1 : 0.870 : 0.511
Z
2
Morphology

Tabular to elongated crystals, sub=parallel aggregates.

Type-locality form

Crystals up to 15 mm long forming subparallel aggregates in rhodonite ore.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
56BaBariumBarium4137.327549.308
31.86%
8OOxygenOxygen3115.999495.969
28.76%
14SiSiliconSilicon828.085224.680
13.03%
23VVanadiumVanadium450.942203.768
11.82%
22TiTitaniumTitanium447.867191.468
11.10%
17ClChlorineChlorine135.45035.450
2.06%
5BBoronBoron210.81021.620
1.25%
1HHydrogenHydrogen21.0082.016
0.12%
Total1724.279100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mn
  • H2O

Synonyms

  • IMA1977-045
  • Nagashimaliet
  • Nagashimalit

In other languages

German
IMA 1977-045 · Nagashimalith
Spanish
nagashimalita
Italian
Nagashimalite
Japanese
長島石

Classification

Strunz
10th ed.

9.CE.20

  • 9SilicatesClass
  • 9.CCyclosilicatesDivision
  • 9.CE[Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anionsGroup
  • 9.CE.20NagashimaliteSpecies
Dana
8th ed.

64.03.01.03

  • 64Cyclosilicates Rings with Other Anions and Insular Silicate GroupsClass
  • 64.03Rings with Other Anions and Insular Silicate Groups: 4-membered rings with [Si2O7] dimersType
  • 64.03.01Taramellite groupGroup
  • 64.03.01.03NagashimaliteSpecies
CIM

17.5.36

  • 17Silicates Containing other AnionsClass
  • 17.5BorosilicatesGroup
  • 17.5.36NagashimaliteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1980Matsubara Satoshi, Kato, Akira (1980) Nagashimalite, Ba4(V3+,Ti)4[(O,OH)2|Cl|Si8B2O27], a new mineral from the Mogurazawa mine, gumma prefecture, Japan. Mineralogical Journal, 10 (3) 122-130 doi:10.2465/minerj.10.122 DOI: 10.2465/minerj.10.122
  2. 1980Matsubara, Satoshi (1980) The crystal structure of nagashimalite, Ba4(V3+,Ti)4[(O,OH)2|Cl|Si8B2O27]. Mineralogical Journal, 10 (3) 131-142 doi:10.2465/minerj.10.131 DOI: 10.2465/minerj.10.131
  3. 1981Fleischer, Michael, Cabri, Louis J. (1981) New Mineral Names. American Mineralogist, 66 (5-6) 637-639
  4. 1996Grew, Edward S.; Anovitz, Lawrence M. - Eds. (1996) Boron - Mineralogy, Petrology and Geochemistry. Reviews in Mineralogy Vol. 33. Mineralogical Society of America p.862
  5. 2001(2001) Nagashimalite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Nagashimalite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/nagashimalite-2828},
  note      = {Accessed 2026-05-11}
}