Napoliite

Pb2OFCl
IMA status
  • Approved
IMA symbol
Npi
Also known as
  • IMA2022-073
  • Napoliiet

Where it forms, where it's found

Geological setting

fumarole formed subsequent to the 1944 eruption of Vesuvius volcano

Type locality
Vesuvius fumaroles
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
colorless
Streak
white
Tenacity
brittle
Cleavage
Perfect

(001)

laminated fracture

Fracture
Micaceous
Density
7.797 g/cm³

Optical

Optical type
Uniaxial
Pleochroism
Non-pleochroic
Optical colour
grey
Anisotropism
very weakly anisotropic
Bireflectance
none
Internal reflections
none
UV response
none
Notes

The Gladstone-Dale relationship predicts an average RI of 2.10

Crystallography

Crystal system
Tetragonal
Space group
P42/mcm
Cell parameters
a = 5.742(1) Å · c = 12.524(4) Å
Z
4
Type-locality form

well-shaped lamellar crystals up to 0.25 x 0.25 x 0.01 mm typically forming clusters up to 0.4 x 0.4 mm on the surface of volcanic scoria

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead2207.200414.400
85.47%
17ClChlorineChlorine135.45035.450
7.31%
9FFluorineFluorine118.99818.998
3.92%
8OOxygenOxygen115.99915.999
3.30%
Total484.847100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2022-073
  • Napoliiet

In other languages

German
IMA 2022-073 · Napoliit

Classification

Strunz
10th ed.

3.DC

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DCWith Pb (As,Sb,Bi), without CuGroup
  • 3.DCNapoliiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 2022Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2022) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 70. European Journal of Mineralogy, 34 (6) 591-601 doi:10.5194/ejm-34-591-2022 DOI: 10.5194/ejm-34-591-2022
  2. 2023Kasatkin, Anatoly V., Siidra, Oleg I., Nestola, Fabrizio, Pekov, Igor V., Agakhanov, Atali A., Koshlyakova, Natalia N., Chukanov, Nikita V., Nazarchuk, Evgeny V., Molinari, Simone, Rossi, Manuela (2023) Napoliite, Pb2OFCl, a new mineral from Vesuvius volcano, and its relationship with dimorphous rumseyite. Mineralogical Magazine, 87 (5) 711-718 doi:10.1180/mgm.2023.43DOI: 10.1180/mgm.2023.43
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Napoliite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/napoliite-470499},
  note      = {Accessed 2026-05-11}
}