Natroaphthitalite

KNa3(SO4)2
IMA status
  • Approved
IMA symbol
Natt
IMA approved
2018
Also known as
  • IMA2018-091
  • Natroaphthitaliet

Where it forms, where it's found

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

1recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Translucent
Colour
yellow to colorless
Density
2.664 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.488 – 1.49
Surface relief
Low
Principal indices
nω 1.488 · nε 1.490
Michel-Lévy diagramhighlighted lineδ = 0.0020
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]20 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation20 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
P-3m1
Cell parameters
a = 5.6014(3) Å · c = 7.1507(5) Å
Z
1
Type-locality form

single-crystal individuals up to 1 cm in diameter, sometimes combined in crusts up to 2 cm across, and as aqua-transparent colorless tabular to lamellar hexagonal crystals up to 2 mm across, sometimes skeletal, typically combined in parallel intergrowths

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen815.999127.992
42.64%
11NaSodiumSodium322.99068.970
22.98%
16SSulfurSulfur232.06064.120
21.36%
19KPotassiumPotassium139.09839.098
13.02%
Total300.180100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2018-091
  • Natroaphthitaliet

In other languages

German
Natroaphthitalit

Classification

Strunz
10th ed.

7.AC.35

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.ACWith medium-sized and large cationsGroup
  • 7.AC.35NatroaphthitaliteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 2018Hålenius, Ulf, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2018) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) NEWSLETTER 46. European Journal of Mineralogy, 30 (6) 1181-1189 doi:10.1127/ejm/2018/0030-2819DOI: 10.1127/ejm/2018/0030-2819
  2. 2020Shchipalkina, Nadezhda V., Pekov, Igor V., Chukanov, Nikita V., Belakovskiy, Dmitry I., Zubkova, Natalia V., Koshlyakova, Natalia N., Britvin, Sergey N., Sidorov, Evgeny G. (2020) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik volcano, Kamchatka, Russia. II. A new mineral, natroaphthitalite, and new data on belomarinaite. The Canadian Mineralogist, 58 (2). 167-181 doi:10.3749/canmin.1900076DOI: 10.3749/canmin.1900076
  3. 2022(2022) Natroaphthitalite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Natroaphthitalite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/natroaphthitalite-53216},
  note      = {Accessed 2026-05-11}
}