Aphthitalite

K3Na(SO4)2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Att
Discovered
1813
Also known as
  • Aftalosa
  • Aftalosia
  • Aftalosio
  • +17 more

Where it forms, where it's found

Geological setting

Volcanic fumaroles

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
95recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent · Opaque
Colour
Colourless (rare) · white · grey · bluish · greenish · reddish · colourless in transmitted light
Streak
White
Tenacity
brittle
Cleavage
Imperfect/Fair

On (1010) fair; on (0001) poor.

Fracture
Irregular/Uneven · Conchoidal
Density
2.656 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.487 – 1.499
Surface relief
Low
Principal indices
nω 1.487 – 1.491 · nε 1.492 – 1.499
Michel-Lévy diagramhighlighted lineδ = 0.0065
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]65 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation65 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
P-3m1
Cell parameters
a = 5.677 Å · c = 7.3331 Å
Z
1
Morphology

Crystals commonly thin to thick tabular with pronounced trigonal development. Distorted pseudo-orthorhombic forms. Bladed aggregates; mammilary; crusts; massive.

Twinning

On (0001) or on (1120), repeated. Twinned groups on (1120), similar to aragonite twins.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen815.999127.992
38.50%
19KPotassiumPotassium339.098117.294
35.29%
16SSulfurSulfur232.06064.120
19.29%
11NaSodiumSodium122.99022.990
6.92%
Total332.396100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Aftalosa
  • Aftalosia
  • Aftalosio
  • Aftitalit
  • Aftitalitt
  • Aphtalita
  • Aphtalite
  • Aphtalith
  • Aphthitaliet
  • Aphthitalita
  • Aphthitalith
  • Aphtitalith
  • Arcanit (of Haidinger)
  • Glaserit
  • Glaserita
  • Glaserite
  • Sal polychrestum Glaseri
  • Schwefelkalisalz
  • Solfato potassico
  • Vesuvian Salt

In other languages

French
Aphthalose
German
Aphthitalit
Spanish
Aftitalita · glaserita
Italian
aftitalite
Chinese
鉀芒硝

Classification

Strunz
10th ed.

7.AC.35

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.ACWith medium-sized and large cationsGroup
  • 7.AC.35AphthitaliteSpecies
Dana
8th ed.

28.02.02.01

  • 28Anhydrous Acid and Normal SulfatesClass
  • 28.02A2XO4Type
  • 28.02.02— unnamed intermediate level —Group
  • 28.02.02.01AphthitaliteSpecies
CIM

25.1.7

  • 25SulphatesClass
  • 25.1Sulphates of the alkali metals and ammoniumGroup
  • 25.1.7AphthitaliteSpecies

Group, growth & confusion

Often grow together
6 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1813Smithson, J. (1813) On a saline substance from Mount Vesuvius. Royal Society of London, Philosophical Transactions: 256-262.
  2. 1813Smithson, J. (1813) On a saline substance from Mount Vesuvius. Royal Society of London, Philosophical Transactions: 256-262. [as Vesuvian Salt]
  3. 1832Shepard, C.U. (1832) Aphthitalite. Treatise on Mineralogy. First edition: vol. 1, New Haven: 36.
  4. 1832Beudant, François-Sulpice (1832) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 2 - Tome II [Volume II]. Chez Verdière.
  5. 1839Glocker, E.F. (1839) Handbuch der Mineralogie, 2nd. edition, Nürnberg: 676. [as Schwefelkalisalz]
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Aphthitalite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/aphthitalite-280},
  note      = {Accessed 2026-05-11}
}