Navajoite

(V5+,Fe3+)10O24 · 12H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Nvj
Discovered
1954
Also known as
  • Navajoiet

Where it forms, where it's found

Geological setting

Colorado Plateau U-V deposit. Forming seams in sandstone and crescent-shaped coatings above and below conglomerate pebbles.

Type locality
Monument No. 2 Mine
  1. Monument No. 2 channel
  2. Yazzie Mesa
  3. Cane Valley Mining District
  4. Apache County
  5. Arizona
  6. USA

36.9264°, -109.8888°

14recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Dark brown
Streak
Light brown
Tenacity
sectile
Density
2.56 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
1.905 – 2.02
Surface relief
Very high
Principal indices
nα 1.905 · nβ 2.02 · nγ 2.02
Pleochroism
Visible

X = Y = yellowish brown; Z = dark brown.

Dispersion
Dispersion not observed
Extinction
Z = b.
Michel-Lévy diagramhighlighted lineδ = 0.1150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1150 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1150 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 34.94(2) Å · b = 3.597(2) Å · c = 11.79(1) Å
Cell angles
β = 95.98(6) °
Ratio a:b:c
1 : 0.103 : 0.337
Z
2
Morphology

Fibrous cross vein fillings.

Type-locality form

Brown fibrous seams and coatings, with fibers perpendicular to the wall rock.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3615.999575.964
34.53%
26FeIronIron1055.845558.450
33.48%
23VVanadiumVanadium1050.942509.420
30.54%
1HHydrogenHydrogen241.00824.192
1.45%
Total1668.026100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Navajoiet

In other languages

German
Navajoit
Spanish
Navajoíta
Italian
Navajoite

Classification

Strunz
10th ed.

4.HG.30

  • 4OxidesClass
  • 4.HV[5,6] VanadatesDivision
  • 4.HGUnclassified V oxidesGroup
  • 4.HG.30NavajoiteSpecies
Dana
8th ed.

04.06.02.01

  • 04Simple OxidesClass
  • 04.06MiscellaneousType
  • 04.06.02— unnamed intermediate level —Group
  • 04.06.02.01NavajoiteSpecies
CIM

7.12.8

  • 7Oxides and HydroxidesClass
  • 7.12Oxides of V, Nb and TaGroup
  • 7.12.8NavajoiteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1954Weeks, A. D., Thompson, M. E., Sherwood, A. M. (1954) Navajoite, a New Vanadium Oxide from Arizona. Science, 119 (3088) 326 doi:10.1126/science.119.3088.326DOI: 10.1126/science.119.3088.326
  2. 1955Weeks, Alice D., Thompson, Mary E., Sherwood, Alexander W. (1955) Navajoite, a new vanadium oxide from Arizona. American Mineralogist, 40 (3-4) 207-212
  3. 1977Theobald, F. (1977): A comparison of natural and synthetic vanadium oxyhydroxides. Bulletin de la Société Chimique de France 1977 (9-10, Pt. 1), 803-807.
  4. 1990Evans, Howard T., Jr.,, Hughes, John M. (1990) Crystal chemistry of the natural vanadium bronzes. American Mineralogist, 75 (5-6) 508-521
  5. 2005(2005) Navajoite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Navajoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/navajoite-2867},
  note      = {Accessed 2026-05-11}
}