Nitrocalcite

Ca(NO3)2 · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ncal
Discovered
1835
Also known as
  • Aphronatrum
  • Aphronitrum
  • Calcinitre
  • +6 more

Where it forms, where it's found

Geological setting

Efflorescences in limestone caves or upon calcareous rocks and soils.

Type locality
Nicajack Cave (Nicojack Cave)
  1. Marion County
  2. Tennessee
  3. USA
19recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
White · grey · colourless in transmitted light
Cleavage
Imperfect/Fair

observed

Density
1.90 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 48 – 52°
Refractive index
1.465 – 1.504
Surface relief
Low
Principal indices
nα 1.465 · nβ 1.498 · nγ 1.504
Dispersion
r > v strong
Michel-Lévy diagramhighlighted lineδ = 0.0390
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]390 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation390 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 14.8999(12) Å · b = 9.1551(5) Å · c = 6.2786(7) Å
Cell angles
β = 106.22(1) °
Ratio a:b:c
1 : 0.614 : 0.421
Z
4
Morphology

Efflorescent crusts, tufts and masses; rarely as acicular crystals. Artificial crystals long prismatic [001].

Comment

Space Group: P21/n (synthetic).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1015.999159.990
67.75%
20CaCalciumCalcium140.07840.078
16.97%
7NNitrogenNitrogen214.00728.014
11.86%
1HHydrogenHydrogen81.0088.064
3.42%
Total236.146100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Aphronatrum
  • Aphronitrum
  • Calcinitre
  • Calcium Nitrate
  • Kalksalpeter
  • Nitrate de chaux
  • Nitrate of lime
  • Nitre à base calcaire
  • Nitrocalciet

In other languages

German
Nitrocalcit
Italian
Nitrocalcite

Classification

Strunz
10th ed.

5.NC.10

  • 5CarbonatesClass
  • 5.NNITRATESDivision
  • 5.NCWith H2OGroup
  • 5.NC.10NitrocalciteSpecies
Dana
8th ed.

18.02.02.01

  • 18Normal NitratesClass
  • 18.02A(XO3)2·xH2O, where x can equal zeroType
  • 18.02.02— unnamed intermediate level —Group
  • 18.02.02.01NitrocalciteSpecies
CIM

13.5

  • 13NitratesClass
  • 13.5— unnamed intermediate level —Group
  • 13.5NitrocalciteSpecies

Group, growth & confusion

Often grow together
3 minerals

Literature, links & citation

Citations
  1. 1783Lisle, Jean-Baptiste-Louis Romé de, Romé de L'Isle, Jean-Baptiste Louis de (1783) Cristallographie, ou Description des formes propres à tous les corps du règne minéral dans l'état de combinaison saline, pierreuse ou métallique [Crystallography, or Description of the forms specific to all bodies of the mineral kingdom in the state of saline, stony or metallic combination] (2nd ed.). L'Imprimerie de Monsieur.
  2. 1813Hausmann, Johann Friedrich Ludwig (1813) Handbuch der Mineralogie (1st ed.). Vandenhoeck und Ruprecht.
  3. 1824Beudant, François-Sulpice (1824) Traité élémentaire de minéralogie. (Première Edition)) [Elementary Treatise on Mineralogy. (First Edition)]. Chez Verdière.
  4. 1832Beudant, François-Sulpice (1832) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 2 - Tome II [Volume II]. Chez Verdière.
  5. 1835Shepard C.U. (1835) Nitrocalcite. Calcareous earthy-salt. in Treatise on Mineralogy. First edition: vol. 1, New Haven (1832); vols. 2: 84.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Nitrocalcite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/nitrocalcite-2919},
  note      = {Accessed 2026-05-11}
}