Papagoite

CaCuAlSi2O6(OH)3
IMA status
  • Approved
IMA symbol
Pap
Discovered
1960

Where it forms, where it's found

Geological setting

Metasomatic rocks. Altered granodiorite porphyry.

Type locality
New Cornelia Mine
  1. Ajo
  2. Little Ajo Mountains
  3. Ajo Mining District
  4. Pima County
  5. Arizona
  6. USA

32.3556°, -112.8650°

6recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Blue · cerulean blue
Cleavage
Distinct/Good

On (100), noted in thin sections but not in crystals.

Density
3.25 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 78° · 2V calc = 84°
Refractive index
1.607 – 1.672
Surface relief
Moderate
Principal indices
nα 1.607 · nβ 1.641 · nγ 1.672
Pleochroism
Strong

X = colorless to very pale greenish blue; Y = blue; Z = deep greenish blue.

Dispersion
r < v
Notes

Z > Y > X. Z = b; X Λ c = 44°.

Michel-Lévy diagramhighlighted lineδ = 0.0650
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]650 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation650 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 12.926(3) Å · b = 11.496(3) Å · c = 4.696(1) Å
Cell angles
β = 100.81(2) °
Ratio a:b:c
1 : 0.889 : 0.363
Z
4
Morphology

Type material: Roughly equidimensional, slightly flattened parallel to (001). Faces in the zone [010] well developed. Forms include dominant (001), (401), (110) and less dominant (102), (101), (201), (601), and (100).

Type-locality form

Narrow veinlets and veneers on slip-surfaces in an altered rock. Roughly equi-dimensional crystals, less than 1 mm in length.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen915.999143.991
43.14%
29CuCopperCopper163.54663.546
19.04%
14SiSiliconSilicon228.08556.170
16.83%
20CaCalciumCalcium140.07840.078
12.01%
13AlAluminiumAluminium126.98226.982
8.08%
1HHydrogenHydrogen31.0083.024
0.90%
Total333.791100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Fe
  • Mn
  • Mg
  • H2O

In other languages

French
Papagoïte
German
Papagoit
Spanish
Papagoíta
Italian
Papagoite
Japanese
パパゴ石
Chinese
硅铝铜钙石
Simplified Chinese
硅铝铜钙石
Traditional Chinese
矽鋁銅鈣石 · 矽铝铜钙石

Classification

Strunz
10th ed.

9.CE.05

  • 9SilicatesClass
  • 9.CCyclosilicatesDivision
  • 9.CE[Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anionsGroup
  • 9.CE.05PapagoiteSpecies
Dana
8th ed.

60.01.04.01

  • 60Cyclosilicates Four-membered RingsClass
  • 60.01Four-Membered Rings, as TitanosilicatesType
  • 60.01.04— unnamed intermediate level —Group
  • 60.01.04.01PapagoiteSpecies
CIM

16.5.7

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.5— unnamed intermediate level —Group
  • 16.5.7PapagoiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1960Hutton, C. O., Vlisidis, A. C. (1960) Papagoite, a new copper-bearing mineral from Ajo, Arizona. American Mineralogist, 45 (5-6) 599-611
  2. 1961Fleischer, Michael (1961) New mineral names. American Mineralogist, 46 (3-4). 464-468
  3. 1962(1962) International Mineralogical Association: Commission on New Minerals and Mineral Names. Mineralogical Magazine and Journal of the Mineralogical Society, 33 (258) 260-263 doi:10.1180/minmag.1962.033.258.09 DOI: 10.1180/minmag.1962.033.258.09
  4. 1965Guillebert, Claire, Le Bihan, Marie-Thérèse (1965) Contribution à l'étude structurale des silicates de cuivre : structure atomique de la papagoïte. Bulletin de Minéralogie, 88 (1) 119-121 doi:10.3406/bulmi.1965.5811DOI: 10.3406/bulmi.1965.5811
  5. 1987Groat, L. A., Hawthorne, F. C. (1987) Refinement of the crystal structure of papagoite, CaCuAlSi2O6(OH)3. Mineralogy and Petrology, 37 (2) 89-96 doi:10.1007/bf01164184DOI: 10.1007/bf01164184
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Papagoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/papagoite-3077},
  note      = {Accessed 2026-05-11}
}