Ajoite

K3Cu2+20Al3Si29O76(OH)16 · 8H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Aj
Discovered
1958
Also known as
  • Ajoiet
  • Ajoitt

Where it forms, where it's found

Geological setting

In oxidised copper-rich base-metal deposits.

Type locality
New Cornelia Mine
  1. Ajo
  2. Little Ajo Mountains
  3. Ajo Mining District
  4. Pima County
  5. Arizona
  6. USA

32.3556°, -112.8650°

17recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Translucent
Colour
Bluish green
Streak
Greenish white
Cleavage
Perfect

on (010)

Density
2.96 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 80° · 2V calc = 76.4°
Refractive index
1.55 – 1.641
Surface relief
Moderate
Principal indices
nα 1.550 · nβ 1.583 · nγ 1.641
Pleochroism
Visible

X= very light bluish green Y=Z= brilliant bluish green

Dispersion
r < v strong
Michel-Lévy diagramhighlighted lineδ = 0.0910
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]910 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation910 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Cell parameters
a = 13.634(5) Å · b = 13.687(7) Å · c = 14.522(7) Å
Cell angles
α = 110.83(1) ° · β = 107.21(1) ° · γ = 105.68(1) °
Ratio a:b:c
1 : 1.004 : 1.065
Z
3
Morphology

As sprays of bladed prismatic crystals, to 0.4 mm; commonly fibrous. From New Cornelia mine (010) is the most prominent form and (100) and (110) are much less prominent but always present. The termination on c may be either (001) or (203) or both.

Comment

Cell parameters from Pluth and Smith (2002)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen10015.9991599.900
40.86%
29CuCopperCopper2063.5461270.920
32.46%
14SiSiliconSilicon2928.085814.465
20.80%
19KPotassiumPotassium339.098117.294
2.99%
13AlAluminiumAluminium326.98280.946
2.07%
1HHydrogenHydrogen321.00832.256
0.82%
Total3915.781100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Mn
  • Ca

Synonyms

  • Ajoiet
  • Ajoitt

In other languages

French
ajoïte
German
Ajoit
Spanish
Ajoíta
Italian
ajoite
Russian
Ахоит
Arabic
أجويت

Classification

Strunz
10th ed.

9.EA.70

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EASingle nets of tetrahedra with 4-, 5-, (6-), and 8-membered ringsGroup
  • 9.EA.70AjoiteSpecies
Dana
8th ed.

78.05.01.01

  • 78Unclassified SilicatesClass
  • 78.05Unclassified silicates possible phyllosilicatesType
  • 78.05.01— unnamed intermediate level —Group
  • 78.05.01.01AjoiteSpecies
CIM

16.5.6

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.5— unnamed intermediate level —Group
  • 16.5.6AjoiteSpecies

Group, growth & confusion

Often grow together
4 minerals

Literature, links & citation

Citations
  1. 1958Schaller, W. T., Vlisidis, A. C. (1958) Ajoite, a new hydrous aluminum copper silicate. American Mineralogist, 43 (11-12) 1107-1111
  2. 1976Kato, Toshio, Miúra, Yasunori (1976) Cell dimensions of ajoite. Mineralogical Journal, 8 (4) 234-239 doi:10.2465/minerj.8.234DOI: 10.2465/minerj.8.234
  3. 1981Chao, George Y. (1981) Ajoite: new data. American Mineralogist, 66 (1-2) 201-203
  4. 2002Pluth, J.J., Smith, J.V. (2002) Arizona porphyry copper/hydrothermal deposits II: Crystal structure of ajoite, (K+Na)3Cu20Al3Si29O76(OH)16·~8H2O. Proceedings of the National Academy of Sciences of the United States of America: 99: 11002-11005.
  5. 2002Kolitsch, U. (2002) Unpublished structure refinement.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ajoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ajoite-66},
  note      = {Accessed 2026-05-11}
}