Where it forms, where it's found
- Geological setting
In oxidised copper-rich base-metal deposits.
- Type locality
- New Cornelia Mine
- Ajo
- Little Ajo Mountains
- Ajo Mining District
- Pima County
- Arizona
- USA
32.3556°, -112.8650°
Physical
- Transparency
- Translucent
- Colour
- Bluish green
- Streak
- Greenish white
- Cleavage
- Perfect
on (010)
- Density
- 2.96 g/cm³
Optical
- Optical type
- Biaxial (+) · 2V measured = 80° · 2V calc = 76.4°
- Refractive index
- 1.55 – 1.641
- Surface relief
- Moderate
- Principal indices
- nα 1.550 · nβ 1.583 · nγ 1.641
- Pleochroism
- Visible
X= very light bluish green Y=Z= brilliant bluish green
- Dispersion
- r < v strong
Crystallography
- Cell parameters
- a = 13.634(5) Å · b = 13.687(7) Å · c = 14.522(7) Å
- Cell angles
- α = 110.83(1) ° · β = 107.21(1) ° · γ = 105.68(1) °
- Ratio a:b:c
- 1 : 1.004 : 1.065
- Z
- 3
- Morphology
As sprays of bladed prismatic crystals, to 0.4 mm; commonly fibrous. From New Cornelia mine (010) is the most prominent form and (100) and (110) are much less prominent but always present. The termination on c may be either (001) or (203) or both.
- Comment
Cell parameters from Pluth and Smith (2002)
Chemical composition
- Impurities
- Fe
- Mn
- Ca
Synonyms
- Ajoiet
- Ajoitt
In other languages
- French
- ajoïte
- German
- Ajoit
- Spanish
- Ajoíta
- Italian
- ajoite
- Russian
- Ахоит
- Arabic
- أجويت
Classification
9.EA.70
- 9SilicatesClass
- 9.EPhyllosilicatesDivision
- 9.EASingle nets of tetrahedra with 4-, 5-, (6-), and 8-membered ringsGroup
- 9.EA.70AjoiteSpecies
78.05.01.01
- 78Unclassified SilicatesClass
- 78.05Unclassified silicates possible phyllosilicatesType
- 78.05.01— unnamed intermediate level —Group
- 78.05.01.01AjoiteSpecies
16.5.6
- 16Silicates Containing Aluminum and other MetalsClass
- 16.5— unnamed intermediate level —Group
- 16.5.6AjoiteSpecies
Group, growth & confusion
Literature, links & citation
- 1958Schaller, W. T., Vlisidis, A. C. (1958) Ajoite, a new hydrous aluminum copper silicate. American Mineralogist, 43 (11-12) 1107-1111
- 1976Kato, Toshio, Miúra, Yasunori (1976) Cell dimensions of ajoite. Mineralogical Journal, 8 (4) 234-239 doi:10.2465/minerj.8.234DOI: 10.2465/minerj.8.234
- 1981Chao, George Y. (1981) Ajoite: new data. American Mineralogist, 66 (1-2) 201-203
- 2002Pluth, J.J., Smith, J.V. (2002) Arizona porphyry copper/hydrothermal deposits II: Crystal structure of ajoite, (K+Na)3Cu20Al3Si29O76(OH)16·~8H2O. Proceedings of the National Academy of Sciences of the United States of America: 99: 11002-11005.
- 2002Kolitsch, U. (2002) Unpublished structure refinement.
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Ajoite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/ajoite-66},
note = {Accessed 2026-05-11}
}


