Pararealgar

As4S4
IMA status
  • Approved
IMA symbol
Prlg
Discovered
1980
IMA approved
1980
Also known as
  • IMA1980-034
  • Pararealgaar

Where it forms, where it's found

Type locality
Mt Washington mine
  1. Comox District
  2. Nanaimo Mining Division
  3. Vancouver Island
  4. British Columbia
  5. Canada

49.7633°, -125.3022°

67recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789101 – 1.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous/Resinous
Transparency
Translucent · Opaque
Colour
Light yellow to orange-brown
Streak
Light yellow
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.52 g/cm³

Optical

Pleochroism
Strong
Anisotropism
Distinct
Internal reflections
Gold to orange-red
Tropism
Anisotropic
UV response
Not fluorescent.
Notes

Refractive indices could not be measured but are greater than 2.02.

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 9.909 Å · b = 9.655 Å · c = 8.502 Å
Cell angles
β = 97.20 °
Ratio a:b:c
1 : 0.974 : 0.858
Unit cell volume
806.8 ų
Type-locality form

Powdery to granular fine-grained aggregates that replace realgar.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic474.922299.688
70.03%
16SSulfurSulfur432.060128.240
29.97%
Total427.928100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1980-034
  • Pararealgaar

In other languages

French
Pararealgar
German
Pararealgar
Spanish
Pararrejalgar
Italian
Pararealgar
Chinese
副雄黄 · 四硫化四砷
Russian
тетрасульфид тетрамышьяка

Classification

Strunz
10th ed.

2.FA.15b

  • 2Sulfides and SulfosaltsClass
  • 2.FSulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2ODivision
  • 2.FAWith As, (Sb), SGroup
  • 2.FA.15bPararealgarSpecies
Dana
8th ed.

02.08.21.02

  • 02SulfidesClass
  • 02.08AmXp, with m:p = 1:1Type
  • 02.08.21— unnamed intermediate level —Group
  • 02.08.21.02PararealgarSpecies
CIM

3.7.5

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.7Sulphides etc. of V, As, Sb and BiGroup
  • 3.7.5PararealgarSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1980Roberts, A. C., Ansell, H. G., Bonardi, M. (1980) Pararealgar, a new polymorph of AsS, from British Columbia. The Canadian Mineralogist, 18 (3) 525-527
  2. 1992Douglass, D.L., Shing, C., Wang, G. (1992) The light-induced alteration of realgar to pararealgar. American Mineralogist: 77: 1266-1274.
  3. 1995Bonazzi, Paola, Menchetti, Silvio, Pratesi, Giovanni (1995) The crystal structure of pararealgar, As4S4. American Mineralogist, 80 (3) 400-403 doi:10.2138/am-1995-3-422 DOI: 10.2138/am-1995-3-422
  4. 2005Kyono, A., Kimata, M., Hatta, T. (2005) Light-induced degradation dynamics in realgar: In situ structural investigation using single-crystal X-ray diffraction study and X-ray photoelectron spectroscopy. American Mineralogist: 90: 1563-1570.
  5. 2005(2005) Pararealgar. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pararealgar — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pararealgar-3107},
  note      = {Accessed 2026-05-11}
}