Bonazziite

As4S4
IMA status
  • Approved
IMA symbol
Bzz
IMA approved
2013
Also known as
  • Bonazziiet
  • IMA2013-141
  • UM1970-19-S:As
  • +1 more

Where it forms, where it's found

Geological setting

Mercury-antimony low-temperature hydrothermal deposit.

Associated with low temperature epithermal Hg-As-Sb deposits, vapor deposited environments - burning coal or volcanic.

Type locality
Alacrán Mine
  1. Alacrán
  2. Pampa Larga mining district
  3. Tierra Amarilla
  4. Copiapó Province
  5. Atacama
  6. Chile

-27.5969°, -70.1756°

8recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Orange

colour is slightly paler and more yellowish than realgar

Streak
Dark orange
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.542 g/cm³

Optical

Pleochroism
Visible

orange to light red

Anisotropism
strong greyish to light-blue rotation tints.
Internal reflections
orange to red
Tropism
Anisotropic
Reflectance R%
(19.9, 22.2) 471.1, (19.1, 21.3) 548.3, (18.8, 19.7) 586.6, (17.8, 18.9) 652.3
Reflected-light panel
18.9 %anisotropic · dual curve
Specimen sRGB 158, 112, 62
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
strong greyish to light-blue rotation tints.
Internal reflections
orange to red

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 9.956(1) Å · b = 9.308(1) Å · c = 8.869(1) Å
Cell angles
β = 102.55(2) °
Ratio a:b:c
1 : 0.935 : 0.891
Unit cell volume
802.3 ų
Z
4
Type-locality form

Crystals up to 100 μm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic474.922299.688
70.03%
16SSulfurSulfur432.060128.240
29.97%
Total427.928100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bonazziiet
  • IMA2013-141
  • UM1970-19-S:As
  • Unnamed (Beta-Arsenic Sulphide)

In other languages

German
Bonazziit · IMA 2013-141
Italian
bonazziite

Classification

Strunz
10th ed.

2.FA

  • 2Sulfides and SulfosaltsClass
  • 2.FSulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2ODivision
  • 2.FAWith As, (Sb), SGroup
  • 2.FABonazziiteSpecies

Group, growth & confusion

Often grow together
3 minerals
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 2003Bonazzi, Paola, Bindi, Luca, Olmi, Filippo, Menchetti, Silvio (2003) How many alacranites do exist? A structural study of non-stoichiometric As8S9-x crystals. European Journal of Mineralogy, 15 (2) 283-288 doi:10.1127/0935-1221/2003/0015-0283DOI: 10.1127/0935-1221/2003/0015-0283
  2. 2009Carpentier, J.F. & Favreau, G. (2009) β-As4S4 de La Ricamarie, Loire. Le Cahier des Micromonteurs, 103, 12-13.
  3. 2014Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2014) New minerals and nomenclature modifications approved in 2014, CNMNC Newsletter No 20. Mineralogical Magazine, 78 (3) 549-558 doi:10.1180/minmag.2014.078.3.05DOI: 10.1180/minmag.2014.078.3.05
  4. 2015Bindi, Luca, Pratesi, Giovanni, Muniz-Miranda, Maurizio, Zoppi, Matteo, Chelazzi, Laura, Lepore, Giovanni O., Menchetti, Silvio (2015) From ancient pigments to modern optoelectronic applications of arsenic sulfides: bonazziite, the natural analogue of β-As4S4 from Khaidarkan deposit, Kyrgyzstan. Mineralogical Magazine, 79 (1) 121-131 doi:10.1180/minmag.2015.079.1.10DOI: 10.1180/minmag.2015.079.1.10
  5. 2016(2016) Bonazziite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bonazziite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bonazziite-46093},
  note      = {Accessed 2026-05-11}
}