Pekoite

CuPbBi11S18
IMA status
  • Approved
IMA symbol
Pek
Discovered
1975
IMA approved
1975
Also known as
  • IMA1975-014
  • Pekoiet

Where it forms, where it's found

Type locality
Juno Mine ('Peko'
  1. Explorer 8)
  2. Tennant Creek
  3. Barkly Region
  4. Northern Territory
  5. Australia

-19.7024°, 134.2449°

45recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
lead-grey
Streak
lead-grey
Cleavage
Distinct/Good

(010)

Density
6.8 g/cm³

Optical

Optical colour
white to cream

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 11.472(2) Å · b = 33.744(6) Å · c = 4.016(1) Å
Ratio a:b:c
1 : 2.941 : 0.350
Z
2
Type-locality form

Crystals are prismatic, to 2 mm; in banded exsolution intergrowths epitaxial with gladite

Comment

Space Group: P21am.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth11208.9802298.780
73.06%
16SSulfurSulfur1832.060577.080
18.34%
82PbLeadLead1207.200207.200
6.58%
29CuCopperCopper163.54663.546
2.02%
Total3146.606100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ag
  • Fe

Synonyms

  • IMA1975-014
  • Pekoiet

In other languages

German
IMA 1975-014 · Pekoit
Italian
Pekoite

Classification

Strunz
10th ed.

2.HB.05a

  • 2Sulfides and SulfosaltsClass
  • 2.HSulfosalts of SnS archetypeDivision
  • 2.HBWith Cu, Ag, Fe, Sn and PbGroup
  • 2.HB.05aPekoiteSpecies
Dana
8th ed.

03.04.05.06

  • 03SulfosaltsClass
  • 03.04ø = 3Type
  • 03.04.05Aikinite Group (Orthorhombic containing Pb, Cu, Bi, & S)Group
  • 03.04.05.06PekoiteSpecies
CIM

5.7.17

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.7Sulpharsenites etc. of Pb and other metalsGroup
  • 5.7.17PekoiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1976Mumme, William G., Welin, Eric, Weunsch, B. J. (1976) Crystal chemistry and proposed nomenclature for sulfosalts intermediate in the system bismuthinite-aikinite (Bi2S3-CuPbBiS3). American Mineralogist, 61 (1-2). 15-20
  2. 1976Mumme, W.G. and Watts, J.A. (1976) Pekoite, CuPbBi11S18, a new member of the bismuthinite-aikinite mineral series: its crystal structure and relationship with naturally- and synthetically-formed members. Canadian Mineralogist: 14: 322-333.
  3. 1976Mumme, W.G. and Watts, J.A. (1976) Additional physical, optical and x-ray data for pekoite. Canadian Mineralogist: 14: 578.
  4. 1985Birch, W. D., Mumme, W. G. (1985) Pekoite from Narechen, Bulgaria–a possible solution to the bonchevite problem. Mineralogical Magazine, 49 (350) 135-137 doi:10.1180/minmag.1985.049.350.21 DOI: 10.1180/minmag.1985.049.350.21
  5. 1990Mozgova, N. N., Nenasheva, S. N., Chistyakova, N. I., Mogilevkin, S. B., Sivtsov, A. V. (1990) Compositional fields of minerals in the bismuthinite-aikinite series. Neues Jahrbuch für Mineralogie - Monatshefte, 1990. 35-45
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pekoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pekoite-3144},
  note      = {Accessed 2026-05-11}
}