Penfieldite

Pb2Cl3(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pfd
Discovered
1892
Also known as
  • Penfieldiet

Where it forms, where it's found

Geological setting

Seawater modified slag deposits

oxidized hydrothermal lead deposit

Type locality
Lavrion Slag Localities
  1. Lavreotiki
  2. East Attica
  3. Attica
  4. Greece
19recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless · white · yellowish or bluish tints
Streak
White
Cleavage
Distinct/Good

On (0001).

Density
5.82 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
2.13 – 2.21
Surface relief
Very high
Principal indices
nω 2.13 · nε 2.21
Michel-Lévy diagramhighlighted lineδ = 0.0800
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]800 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation800 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#100
Cell parameters
a = 11.28 Å · c = 48.65 Å
Morphology

Crystals usually prismatic [0001] with (1010) or steeply pyramidal; also tabular (0001). Crystals tiny and commonly grouped in parallel position.

Twinning

1. Twin axis [21_30] with (0001) as composition face. Twinned crystals having [0001] in common but turned 21°47' to each other. 2. Twin plane (4154) with the twinned crystals having c and c' almost at right angles.

Type-locality form

Hexagonal crystals to 5 mm in length. With basalt termination or tapering.

Comment

Strongly pronounced subcell: a = 11.393, c = 4.024 A (Merlino et al., 1995)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead2207.200414.400
77.06%
17ClChlorineChlorine335.450106.350
19.78%
8OOxygenOxygen115.99915.999
2.97%
1HHydrogenHydrogen11.0081.008
0.19%
Total537.757100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Penfieldiet

In other languages

German
Penfieldit
Spanish
Penfieldita
Italian
Penfieldite
Russian
Пенфильдит

Classification

Strunz
10th ed.

3.DC.15

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DCWith Pb (As,Sb,Bi), without CuGroup
  • 3.DC.15PenfielditeSpecies
Dana
8th ed.

10.04.01.01

  • 10Oxyhalides and HydroxyhalidesClass
  • 10.04A2(O,OH)XqType
  • 10.04.01— unnamed intermediate level —Group
  • 10.04.01.01PenfielditeSpecies
CIM

8.8.9

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.8Halides of PbGroup
  • 8.8.9PenfielditeSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1892Genth, F.A. (1892) On penfieldite, a new species. American Journal of Science: 144: 260-261.
  2. 1894Penfield, S.L. (1894) Mineralogical Notes. (On the crystallization of penfieldite). American Journal of Science: 48: 114-118.
  3. 1897Goldschmidt (1897) 260.
  4. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
  5. 1941Fleischer, M. (1941) New mineral names. American Mineralogist, 26 (4). 293-294
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Penfieldite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/penfieldite-3146},
  note      = {Accessed 2026-05-11}
}