Laurionite

PbCl(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Lri
Discovered
1887
Also known as
  • Laurioniet
  • Laurionite-2O

Where it forms, where it's found

Geological setting

Saline water acting on lead slags. Oxidation zone in lead deposits.

Type locality
Lavrion Mining District
  1. Lavreotiki
  2. East Attica
  3. Attica
  4. Greece
62recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless · white
Tenacity
flexible
Cleavage
Distinct/Good

distinct on (101).

Density
6.241 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 70° · 2V calc = 90°
Refractive index
2.077 – 2.158
Surface relief
Very high
Principal indices
nα 2.077 · nβ 2.116 · nγ 2.158
Dispersion
r < v strong
Michel-Lévy diagramhighlighted lineδ = 0.0810
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]810 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation810 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 7.1110 Å · b = 9.6987 Å · c = 4.0203 Å
Ratio a:b:c
1 : 1.364 : 0.565
Z
4
Morphology

Crystals elongated [010] thick to thin tabular (100). Often sword-shaped morphology. (100) striated [0_21] at times. Significant form (812) is generally replaced, or accompanied, by vicinal faces. Also lenticular.

Type-locality form

Lath shaped crystals to 5 mm in length

Comment

Non-standard space-group setting Pcmn.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead1207.200207.200
79.80%
17ClChlorineChlorine135.45035.450
13.65%
8OOxygenOxygen115.99915.999
6.16%
1HHydrogenHydrogen11.0081.008
0.39%
Total259.657100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Laurioniet
  • Laurionite-2O

In other languages

French
Laurionite
German
Laurionit
Spanish
Laurionita
Italian
Laurionite

Classification

Strunz
10th ed.

3.DC.05

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DCWith Pb (As,Sb,Bi), without CuGroup
  • 3.DC.05LaurioniteSpecies
Dana
8th ed.

10.02.02.01

  • 10Oxyhalides and HydroxyhalidesClass
  • 10.02A(O,OH)XqType
  • 10.02.02— unnamed intermediate level —Group
  • 10.02.02.01LaurioniteSpecies
CIM

8.8.7

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.8Halides of PbGroup
  • 8.8.7LaurioniteSpecies

Group, growth & confusion

In the same group
6 members
Often grow together
6 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1887Köchlin, R. (1887): Ueber Phosgenit und ein muthmasslich neues Mineral vom Laurion. Annalen des K.K. Naturhistorischen Hofmuseums, 2, 185-190
  2. 1887vom Rath, G. (1887) Berichte Niederrheinische Gesellschaft für Natur und Heilkunde, Bonn: 102: 149.
  3. 1889Köchlin (1889) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 17: 112.
  4. 1889Hintze, C. (1889) Handbuch der Mineralogie. Berlin and Leipzig. 6 volumes: 1 [2B]: 2632.
  5. 1892Dana, Edward Salisbury; Dana, James Dwight (1892) A System of Mineralogy (6th ed.). John Wiley & Sons, Inc.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Laurionite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/laurionite-2343},
  note      = {Accessed 2026-05-11}
}