Petitjeanite

Bi3O(PO4)2(OH)
IMA status
  • Approved
IMA symbol
Pjn
Discovered
1992
IMA approved
1992
Also known as
  • IMA1992-013
  • Petitjeaniet
  • Petitjohnite

Where it forms, where it's found

Geological setting

Silicified barite veins.

Type locality
Bergweg
  1. Gadernheim
  2. Lautertal (Odenwald)
  3. Bergstraße
  4. Darmstadt
  5. Hesse
  6. Germany

49.7090°, 8.7352°

18recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
White to pale pink or yellow · also dark brown to nearly black

Color depends on vanadium content; colorless to pale pink if V-free, yellow if V-rich, may also be dark brown (Jambor et al, 1994).

Streak
White
Fracture
Conchoidal
Density
6.99 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 75°
Refractive index
2.06 – 2.13
Surface relief
Very high
Principal indices
nα 2.06 · nγ 2.13
Dispersion
r < v strong
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0700
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]700 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation700 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 9.798(3) Å · b = 7.250(3) Å · c = 6.866(2) Å
Cell angles
α = 88.28(2) ° · β = 115.27(2) ° · γ = 110.70(3) °
Ratio a:b:c
1 : 0.740 : 0.701
Z
2
Morphology

Tabular on (100), slightly elongate [001], with distinct (010), (001), (011), and minor (110).

Twinning

Common, interpenetrant, by rotation about [010].

Type-locality form

Spherical aggregates or crusts of intergrown crystals to 0.2 mm.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth3208.980626.940
73.77%
8OOxygenOxygen1015.999159.990
18.82%
15PPhosphorusPhosphorus230.97461.948
7.29%
1HHydrogenHydrogen11.0081.008
0.12%
Total849.886100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Pb
  • V
  • As

Synonyms

  • IMA1992-013
  • Petitjeaniet
  • Petitjohnite

In other languages

German
IMA 1992-013 · Petitjeanit
Italian
Petitjeanite

Classification

Strunz
10th ed.

8.BO.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BOWith only large cations, (OH, etc.):RO4 about 1:1Group
  • 8.BO.10PetitjeaniteSpecies
Dana
8th ed.

41.10.10.01

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.10(AB)3(XO4)2ZqType
  • 41.10.10— unnamed intermediate level —Group
  • 41.10.10.01PetitjeaniteSpecies

Group, growth & confusion

In the same group
2 members

Literature, links & citation

Citations
  1. 1993Krause, W., Belendorff, K., Bernhardt, H.-J. (1993) Petitjeanite, Bi3O(OH)(PO4)2, a new mineral, and additional data for the corresponding arsenate and vanadate, preisingerite and schumacherite. Neues Jahrbuch für Mineralogie - Monatshefte, 1993. 487-503
  2. 1994Jambor, J.L.; Puziewicz, J.; Roberts, A.C. (1994) New mineral names. American Mineralogist, 79 (7-8). p.763-767.
  3. 2005(2005) Petitjeanite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2007Rumsey, M. S., Bridges, T. F., Spratt, J. (2007) The First British Occurrence of Petitjeanite at Carrock Mine, Caldbeck Fells, Cumbria. UK Journal of Mines and Minerals 28, 47-50
  5. 2014Losertová, Lenka, Buřival, Zbyněk, Losos, Zdeněk (2014) Waylandit a petitjeanit, dva nové fosfáty pro lokalitu Cetoraz u Pacova (Česká republika) [Waylandite and petitjeanite, two new phosphates for locality Cetoraz near Pacov (Czech Republic)]. Bulletin mineralogicko-petrologického oddělení Národního muzea v Praze, 22 (2) 269-274
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Petitjeanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/petitjeanite-3329},
  note      = {Accessed 2026-05-11}
}