Petrukite

(Cu,Ag)2(Fe,Zn)(Sn,In)S4
IMA status
  • Approved
IMA symbol
Ptk
Discovered
1989
Also known as
  • IMA1985-052
  • Petrukiet

Where it forms, where it's found

Geological setting

In polymetallic veins associated with granitic plutons.

Type locality
Ikuno Mine
  1. Ikuno-cho-ono
  2. Asago City
  3. Hyogo Prefecture
  4. Japan

35.1667°, 134.8250°

17recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Brown to gray
Cleavage
Distinct/Good

Distinct parallel to (110), (100) and (010).

Optical

Pleochroism
Weak

Very faint pleochroism in oil, in shades of greenish brown.

Optical colour
Brown (air) or greenish brown (oil) when zinc content is low. Increasingly gray with increasing zinc content.
Bireflectance
Weak, but measureable.
Tropism
Anisotropic
Reflectance R%
(27.0,27.0) 470, (27.8,27.7) 546, (27.6,27.5) 589, (27.4,27.1) 650
Reflected-light panel
27.5 %anisotropic · dual curve
Specimen sRGB 191, 133, 71
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
Weak, but measureable.
Reflected colour
Brown (air) or greenish brown (oil) when zinc content is low. Increasingly gray with increasing zinc content.

Crystallography

Crystal system
Orthorhombic
Space group
#34
Cell parameters
a = 7.66 Å · b = 6.43 Å · c = 6.26 Å
Ratio a:b:c
1 : 0.839 : 0.817
Parting
Parallel to (001).
Type-locality form

Small, round grains to 240 um in massive galena and sphalerite(Herb claim). Banded with sakuraiite and sphalerite, bands a few hundred microns thick (Ikuno mine), irregular round grains in quartz (Mount Pleasant).

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
47AgSilverSilver2107.868215.736
26.12%
16SSulfurSulfur432.060128.240
15.53%
29CuCopperCopper263.546127.092
15.39%
50SnTinTin1118.710118.710
14.38%
49InIndiumIndium1114.818114.818
13.90%
30ZnZincZinc165.38065.380
7.92%
26FeIronIron155.84555.845
6.76%
Total825.821100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ag

Synonyms

  • IMA1985-052
  • Petrukiet

In other languages

German
Petrukit
Italian
petrukite
Japanese
ペトラック鉱

Classification

Strunz
10th ed.

2.KA.05

  • 2Sulfides and SulfosaltsClass
  • 2.KSulfarsenates, SulfantimonatesDivision
  • 2.KASulfarsenates with (As,Sb)S4 tetrahedraGroup
  • 2.KA.05PetrukiteSpecies
Dana
8th ed.

02.09.18.01

  • 02SulfidesClass
  • 02.09AmBnXp, with (m+n):p = 1:1Type
  • 02.09.18— unnamed intermediate level —Group
  • 02.09.18.01PetrukiteSpecies
CIM

6.1.23

  • 6Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and SulphohalidesClass
  • 6.1Sulphostannates and other sulfides containing SnGroup
  • 6.1.23PetrukiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1973Petruk, W. (1973) Tin sulphides from the deposit of Brunswick Tin mines Limited. The Canadian Mineralogist, 12 (1) 46-54
  2. 1987Kissin, S.A., Owens, D.R. (1987) Joint Annual Meeting of Geological Assoc. of Canada and Mineralogical Assoc. of Canada, Program with Abstracts: 12: 62.
  3. 1989Kissin, S.A., Owens, D.R. (1989) The relatives of stannite in the light of new data. The Canadian Mineralogist, 27 (4) Mineralogical Association of Canada. 673-688
  4. 2005(2005) Petrukite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2005Radosavljevic, Slobodan A., Rakic, Slobodan M., Stojanovic, Jovica N., Radosavljevic-Mihajlovic, Ana S. (2005) Occurrence of Petrukite in Srebrenica Orefield, Bosnia and Herzegovina. Neues Jahrbuch für Mineralogie - Abhandlungen, 181 (1) 21-26 doi:10.1127/0077-7757/2005/0181-0008DOI: 10.1127/0077-7757/2005/0181-0008
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Petrukite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/petrukite-3178},
  note      = {Accessed 2026-05-11}
}