Phillipsite-Na

Na6(Si10Al6)O32 · 12H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Php-Na
Also known as
  • Phillipsiet-Na

Where it forms, where it's found

Type locality
Rupe di Aci Castello
  1. Aci Castello
  2. Metropolitan City of Catania
  3. Sicily
  4. Italy

37.5542°, 15.1495°

29recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104 – 5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Colour
White
Streak
White

Optical

Optical type
Biaxial (+/-) · 2V measured = 60 – 90° · 2V calc = 70 – 72°
Refractive index
1.483 – 1.514
Surface relief
Low
Principal indices
nα 1.483 – 1.505 · nβ 1.484 – 1.511 · nγ 1.486 – 1.514
Dispersion
r > v or r < v
UV response
Not fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0060
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]60 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation60 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/m
Cell parameters
a = 9.96 Å · b = 14.21 Å · c = 14.26 Å
Cell angles
β = 90 °
Ratio a:b:c
1 : 1.427 : 1.432
Z
2
Comment

Space group ?

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4415.999703.956
53.78%
14SiSiliconSilicon1028.085280.850
21.46%
13AlAluminiumAluminium626.982161.892
12.37%
11NaSodiumSodium622.990137.940
10.54%
1HHydrogenHydrogen241.00824.192
1.85%
Total1308.830100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Phillipsiet-Na

In other languages

German
Phillipsit-Na
Italian
phillipsite-Na

Classification

Strunz
10th ed.

9.GC.10

  • 9SilicatesClass
  • 9.GTektosilicates with zeolitic H2O; zeolite familyDivision
  • 9.GCChains of doubly-connected 4-membered ringsGroup
  • 9.GC.10Phillipsite-NaSpecies

Group, growth & confusion

In the same group
3 members

Literature, links & citation

Citations
  1. 1972Galli, Ermanno, Ghittoni, Anna G. Losehi (1972) The crystal chemistry of phillipsites. American Mineralogist, 57 (7-8) 1125-1145
  2. 1974Rinaldi, R., Pluth, J. J., Smith, J. V. (1974) Zeolites of the phillipsite family. Refinement of the crystal structures of phillipsite and harmotome. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 30 (10) 2426-2433 doi:10.1107/s0567740874007242DOI: 10.1107/s0567740874007242
  3. 1998Coombs, Douglas S., Alberti, Alberto, Armbruster, Thomas, Artioli, Gilberto, Colella, Carmine, Galli, Ermanno, Grice, Joel D., Liebau, Friedrich, Mandarino, Joseph A., Minato, Hideo, Nickel, Ernest H., Passaglia, Elio, Peacor, Donald R., Quartieri, Simona, Rinaldi, Romano, Ross, Malcolm, Sheppard, Richard A., Tillmanns, Ekkehart, Vezzalini, Giovanna (1998) Recommended nomenclature for zeolite minerals: report of the subcommittee on zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names. Mineralogical Magazine, 62 (4) 533-571 doi:10.1180/002646198547800 DOI: 10.1180/002646198547800
  4. 2009Gatta, G. D., Cappelletti, P., Rotiroti, N., Slebodnick, C., Rinaldi, R. (2009) New insights into the crystal structure and crystal chemistry of the zeolite phillipsite. American Mineralogist, 94 (1) 190-199 doi:10.2138/am.2009.3032 DOI: 10.2138/am.2009.3032
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Phillipsite-Na — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/phillipsite-na-7229},
  note      = {Accessed 2026-05-11}
}