Picaite

NaCa[AsO3OH][AsO2(OH)2]
IMA status
  • Approved
IMA symbol
Pic
IMA approved
2018
Also known as
  • IMA2018-022
  • Picaiet

Where it forms, where it's found

Type locality
Torrecillas mine
  1. Iquique
  2. Iquique Province
  3. Tarapacá
  4. Chile

-20.9767°, -70.1419°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless
Streak
White
Tenacity
brittle
Cleavage
Perfect

(010) and (001)

Fracture
Step-Like
Density
3.24 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 88° · 2V calc = 87.2°
Refractive index
1.637 – 1.664
Surface relief
High
Principal indices
nα 1.637 · nβ 1.651 · nγ 1.664
Pleochroism
Non-pleochroic
Dispersion
distinct, r< v
UV response
None
Notes

X^b ≈ 18°, Y^a ≈ 10°, Z^c ≈ 48°

Michel-Lévy diagramhighlighted lineδ = 0.0270
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]270 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation270 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 7.2474(4) Å · b = 14.6547(7) Å · c = 7.2624(5) Å
Cell angles
β = 99.520(7) °
Ratio a:b:c
1 : 2.022 : 1.002
Morphology

Blades flattened on (100), elongate on [001] and exhibiting the forms (100), (010), (011), {11-1} and (021).

Twinning

None observed

Type-locality form

Thick blades to about 1 mm in length, typically in parallel intergrowths.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic274.922149.844
43.57%
8OOxygenOxygen815.999127.992
37.22%
20CaCalciumCalcium140.07840.078
11.65%
11NaSodiumSodium122.99022.990
6.68%
1HHydrogenHydrogen31.0083.024
0.88%
Total343.928100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2018-022
  • Picaiet

In other languages

German
IMA 2018-022 · Picait

Classification

Strunz
10th ed.

8.AD.75

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ADWith only large cationsGroup
  • 8.AD.75PicaiteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 2018Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2018) CNMNC Newsletter No. 44, New minerals and nomenclature modifications approved in 2018. Mineralogical Magazine, 82 (4) 1015-1021 doi:10.1180/mgm.2018.148DOI: 10.1180/mgm.2018.148
  2. 2019Kampf, Anthony R., Nash, Barbara P., Celestian, Aaron J., Dini, Maurizio, Molina Donoso, Arturo A. (2019) Camanchacaite, chinchorroite, espadaite, magnesiofluckite, picaite and ríosecoite: six new hydrogen-arsenate minerals from the Torrecillas mine, Iquique Province, Chile. Mineralogical Magazine, 83 (5) 655-671 doi:10.1180/mgm.2019.28 DOI: 10.1180/mgm.2019.28
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Picaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/picaite-52988},
  note      = {Accessed 2026-05-11}
}