Espadaite

Na4Ca3Mg2[AsO3(OH)]2[AsO2(OH)2]10(H2O)6 · H2O
IMA status
  • Approved
IMA symbol
Esp
IMA approved
2018
Also known as
  • Espadaiet
  • IMA2018-089

Where it forms, where it's found

Type locality
Torrecillas mine
  1. Iquique
  2. Iquique Province
  3. Tarapacá
  4. Chile

-20.9767°, -70.1419°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless
Streak
White
Tenacity
brittle
Cleavage
Perfect

Perfect on (001)

Fracture
Sub-Conchoidal
Density
2.73 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 44° · 2V calc = 43°
Refractive index
1.531 – 1.574
Surface relief
Moderate
Principal indices
nα 1.531 · nβ 1.568 · nγ 1.574
Pleochroism
Non-pleochroic
Dispersion
r < v, very slight
UV response
None
Notes

X = c; Y = a; Z = b

Michel-Lévy diagramhighlighted lineδ = 0.0430
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]430 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation430 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Ccca
Cell parameters
a = 12.3649(10) Å · b = 22.181(2) Å · c = 18.3292(13) Å
Ratio a:b:c
1 : 1.794 : 1.482
Unit cell volume
5027.1 ų
Z
4
Morphology

Blades, flattened on (001) and elongate on [100], exhibiting the forms (001), (010), (110) and (111).

Twinning

None observed

Type-locality form

Blades to about 0.2 mm in length, forms fans, jumbled sprays and random intergrowths

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic1274.922899.064
43.31%
8OOxygenOxygen5515.999879.945
42.38%
20CaCalciumCalcium340.078120.234
5.79%
11NaSodiumSodium422.99091.960
4.43%
12MgMagnesiumMagnesium224.30548.610
2.34%
1HHydrogenHydrogen361.00836.288
1.75%
Total2076.101100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Espadaiet
  • IMA2018-089

In other languages

German
Espadait · IMA 2018-089

Classification

Strunz
10th ed.

8.CF

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CFWith large and medium-sized cations, RO4:H2O > 1:1Group
  • 8.CFEspadaiteSpecies

Group, growth & confusion

Often grow together
6 minerals

Literature, links & citation

Citations
  1. 2018Hålenius, Ulf, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2018) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) NEWSLETTER 46. European Journal of Mineralogy, 30 (6) 1181-1189 doi:10.1127/ejm/2018/0030-2819DOI: 10.1127/ejm/2018/0030-2819
  2. 2019Kampf, Anthony R., Nash, Barbara P., Celestian, Aaron J., Dini, Maurizio, Molina Donoso, Arturo A. (2019) Camanchacaite, chinchorroite, espadaite, magnesiofluckite, picaite and ríosecoite: six new hydrogen-arsenate minerals from the Torrecillas mine, Iquique Province, Chile. Mineralogical Magazine, 83 (5) 655-671 doi:10.1180/mgm.2019.28 DOI: 10.1180/mgm.2019.28
  3. 2022(2022) Espadaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Espadaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/espadaite-53215},
  note      = {Accessed 2026-05-11}
}