Picropharmacolite

Ca4Mg(AsO3OH)2(AsO4)2 · 11H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ppm
Discovered
1819
Also known as
  • Picropharmacoliet
  • Picropharmacolit
  • Pikropharmakolit

Where it forms, where it's found

Geological setting

Surface weathering of arsenic-bearing ores on a mineral mine dump

A secondary mineral found in the oxidized zones of metal ore deposits rich in arsenic; usually post-mine.

Type locality
Ore dumps
  1. Richelsdorf Smelter
  2. Süß
  3. Nentershausen
  4. Hersfeld-Rotenburg
  5. Kassel Region
  6. Hesse
  7. Germany
105recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
White · colorless in transmitted light.
Streak
White
Tenacity
fragile
Cleavage
Perfect

On (100) and (010), perfect.

Fracture
Fibrous · Micaceous
Density
2.55 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 50°
Refractive index
1.556 – 1.585
Surface relief
Moderate
Principal indices
nα 1.556 – 1.566 · nβ 1.566 – 1.571 · nγ 1.577 – 1.585
Birefringence
0.020
Pleochroism
Non-pleochroic
Dispersion
r < v strong
Extinction
Z ^ c = 8°-15°, X=b
UV response
Not fluorescent.
Notes

Earlier reports of higher refractive indices probably made erroneously on another species.

Michel-Lévy diagramhighlighted lineδ = 0.0200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]200 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation200 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
P-1
Cell parameters
a = 13.547 Å · b = 13.500 Å · c = 6.710 Å
Cell angles
α = 99.85 ° · β = 96.41 ° · γ = 91.60 °
Ratio a:b:c
1 : 0.997 : 0.495
Z
2
Morphology

Crystals are most commonly acicular and in radial to divergent clusters, rarely as rectangular prisms elongated on [001]; more typically open spherical clusters to botryoidal with a radiating foliated internal structure, or as fibrous aggregates.

Twinning

None reported.

Comment

Am Min (1981) 66:385 structure.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2715.999431.973
45.93%
33AsArsenicArsenic474.922299.688
31.87%
20CaCalciumCalcium440.078160.312
17.05%
12MgMagnesiumMagnesium124.30524.305
2.58%
1HHydrogenHydrogen241.00824.192
2.57%
Total940.470100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Picropharmacoliet
  • Picropharmacolit
  • Pikropharmakolit

In other languages

French
picropharmacolite
German
Pikropharmakolith
Spanish
Picrofarmacolita
Italian
Picrofarmacolite

Classification

Strunz
10th ed.

8.CH.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CHWith large and medium-sized cations, RO4:H2O < 1:1Group
  • 8.CH.15PicropharmacoliteSpecies
Dana
8th ed.

39.02.04.01

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.02(AB)5[HXO4]2[XO4]2.xH2OType
  • 39.02.04— unnamed intermediate level —Group
  • 39.02.04.01PicropharmacoliteSpecies
CIM

20.2.21

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.2Arsenates of Be, Mg, Ca or BaGroup
  • 20.2.21PicropharmacoliteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1819Stromeyer, H. (1819) Chemische Untersuchung der natürlichen Boraxsäure, des Eisenpecherzes, des Picro-Pharmacoliths und des Polyhalits, eines neuen fossilen-Salzes. Annalen der Physik: 61: 177-189 (185).
  2. 1873Frenzel (1873) Jb. Min.: 786.
  3. 1890Genth (1890) American Journal of Science: 40: 204.
  4. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Picropharmacolite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/picropharmacolite-3207},
  note      = {Accessed 2026-05-11}
}