Where it forms, where it's found
- Geological setting
Surface weathering of arsenic-bearing ores on a mineral mine dump
A secondary mineral found in the oxidized zones of metal ore deposits rich in arsenic; usually post-mine.
- Type locality
- Ore dumps
- Richelsdorf Smelter
- Süß
- Nentershausen
- Hersfeld-Rotenburg
- Kassel Region
- Hesse
- Germany
Safety & handling
Physical
Optical
- Optical type
- Biaxial (+) · 2V measured = 50°
- Refractive index
- 1.556 – 1.585
- Surface relief
- Moderate
- Principal indices
- nα 1.556 – 1.566 · nβ 1.566 – 1.571 · nγ 1.577 – 1.585
- Birefringence
- 0.020
- Pleochroism
- Non-pleochroic
- Dispersion
- r < v strong
- Extinction
- Z ^ c = 8°-15°, X=b
- UV response
- Not fluorescent.
- Notes
Earlier reports of higher refractive indices probably made erroneously on another species.
Crystallography
- Space group
- P-1
- Cell parameters
- a = 13.547 Å · b = 13.500 Å · c = 6.710 Å
- Cell angles
- α = 99.85 ° · β = 96.41 ° · γ = 91.60 °
- Ratio a:b:c
- 1 : 0.997 : 0.495
- Z
- 2
- Morphology
Crystals are most commonly acicular and in radial to divergent clusters, rarely as rectangular prisms elongated on [001]; more typically open spherical clusters to botryoidal with a radiating foliated internal structure, or as fibrous aggregates.
- Twinning
None reported.
- Comment
Am Min (1981) 66:385 structure.
Chemical composition
Synonyms
- Picropharmacoliet
- Picropharmacolit
- Pikropharmakolit
In other languages
- French
- picropharmacolite
- German
- Pikropharmakolith
- Spanish
- Picrofarmacolita
- Italian
- Picrofarmacolite
Classification
8.CH.15
- 8Phosphates, Arsenates, VanadatesClass
- 8.CPhosphates without additional anions, with H2ODivision
- 8.CHWith large and medium-sized cations, RO4:H2O < 1:1Group
- 8.CH.15PicropharmacoliteSpecies
39.02.04.01
- 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
- 39.02(AB)5[HXO4]2[XO4]2.xH2OType
- 39.02.04— unnamed intermediate level —Group
- 39.02.04.01PicropharmacoliteSpecies
20.2.21
- 20Arsenates (also arsenates with phosphate, but without other anions)Class
- 20.2Arsenates of Be, Mg, Ca or BaGroup
- 20.2.21PicropharmacoliteSpecies
Group, growth & confusion
Literature, links & citation
- 1819Stromeyer, H. (1819) Chemische Untersuchung der natürlichen Boraxsäure, des Eisenpecherzes, des Picro-Pharmacoliths und des Polyhalits, eines neuen fossilen-Salzes. Annalen der Physik: 61: 177-189 (185).
- 1873Frenzel (1873) Jb. Min.: 786.
- 1890Genth (1890) American Journal of Science: 40: 204.
- 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
- 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Picropharmacolite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/picropharmacolite-3207},
note = {Accessed 2026-05-11}
}