Polhemusite

(Zn,Hg)S
IMA status
  • Approved
IMA symbol
Phe
Discovered
1978
Also known as
  • IMA1972-017
  • Polhemusiet

Where it forms, where it's found

Type locality
B & B deposit (Dundee)
  1. Big Creek Mining District
  2. Valley County
  3. Idaho
  4. USA

45.0621°, -115.4132°

11recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Black
Cleavage
Imperfect/Fair

Rare

Density
4.83 g/cm³

Optical

Pleochroism
Visible

Distinct in air, very slightly brownish gray to slightly lavender gray. Conspicuous in oil,light brownish gray (almost yellow) to purplish gray.

Optical colour
Gray in air, darker in oil
Anisotropism
Distinct in air, strong in oil
Bireflectance
Decreases with increasing wavelength. Nearly absent at 650 nm.
Internal reflections
Air: strong, lavender, pink, reddish orange, dark red; Oil: strong, red-orange; not visible in all grains
Tropism
Anisotropic
Reflectance R%
(20.1,24.4) 470, (17.1,18.3) 546, (16.5,17.7) 589, (17.9,17.9) 650
Reflected-light panel
17.9 %anisotropic · dual curve
Specimen sRGB 153, 107, 64
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
Decreases with increasing wavelength. Nearly absent at 650 nm.
Anisotropism
Distinct in air, strong in oil
Reflected colour
Gray in air, darker in oil
Internal reflections
Air: strong, lavender, pink, reddish orange, dark red; Oil: strong, red-orange; not visible in all grains

Crystallography

Crystal system
Tetragonal
Cell parameters
a = 8.71 Å · c = 24.74 Å
Z
24
Twinning

Knee-shaped twins resembling those of rutile are common; other simple twins and some lamellar twins are present.

Parting
Rare
Type-locality form

Stubby tetragonal prisms, dipyramids, and irregular grains.

Comment

Point Group: 4/m or 4/m 2/m 2/m.; Space Group: P4/n, P42/n, P4/nbm, P4/nmm, P42/nnm, or P42/ncm; Z = 24 − 32(?)

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
80HgMercuryMercury1200.592200.592
67.30%
30ZnZincZinc165.38065.380
21.94%
16SSulfurSulfur132.06032.060
10.76%
Total298.032100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe

Synonyms

  • IMA1972-017
  • Polhemusiet

In other languages

German
IMA 1972-017 · Polhemusit
Italian
Polhemusite

Classification

Strunz
10th ed.

2.CB.05c

  • 2Sulfides and SulfosaltsClass
  • 2.CMetal Sulfides, M: S = 1: 1 (and similar)Division
  • 2.CBWith Zn, Fe, Cu, Ag, etc.Group
  • 2.CB.05cPolhemusiteSpecies
Dana
8th ed.

02.08.03.01

  • 02SulfidesClass
  • 02.08AmXp, with m:p = 1:1Type
  • 02.08.03— unnamed intermediate level —Group
  • 02.08.03.01PolhemusiteSpecies
CIM

3.5.10

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.5Sulphides etc. of Hg and TlGroup
  • 3.5.10PolhemusiteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1960Wachtel, A. (1960) (Zn,Hg)S and (Zn,Cd,Hg)S Electroluminescent Phosphors. Journal of the Electrochemical Society, 107. 682pp. doi:10.1149/1.2427808DOI: 10.1149/1.2427808
  2. 1978Leonard, B. F., Desborough, George A., Mead, Cynthia W. (1978) Polhemusite, a new Hg-Zn sulfide from Idaho. American Mineralogist, 63 (11-12) 1153-1161
  3. 1984Dumas, J.P., Bougarfa, L., Bensaid, J. (1984) Changements de phases durant l'électrolyse des systèmes Hg-Tl, Hg-Sn, Hg-Pb et Hg-Zn. Journal de Physique, 45. 1543-1548 doi:10.1051/jphys:019840045090154300DOI: 10.1051/jphys:019840045090154300
  4. 1998Hansen, S.C. (1998) Thermodynamic assessment of binary Zn-Hg, Cd-Hg, and In-Hg amalgams. Calphad, 22 (3). 359-373 doi:10.1016/s0364-5916(98)00036-4DOI: 10.1016/s0364-5916(98)00036-4
  5. 2002Okamoto, H. (2002) Hg-Zn (Mercury-Zinc). Journal of Phase Equilibria, 23 (2). 196 doi:10.1361/1054971023604008DOI: 10.1361/1054971023604008
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Polhemusite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/polhemusite-3253},
  note      = {Accessed 2026-05-11}
}