Sphalerite

ZnS
IMA status
  • Approved
  • Grandfathered
IMA symbol
Sp
Discovered
1847
Also known as
  • Beta zinc sulfide
  • Blackjack Zinc
  • Blende
  • +12 more

History

The name sphalerite carries a small joke about miners' frustration. Dark varieties looked so much like galena, the lead ore, that miners would dig them up only to find no lead. The German word for it was blende — from blind or deceiving — long before any scholar wrote it down.

Between the 7th and 16th century CE, smiths used the zinc in sphalerite to make brass. They heated the ore alongside copper to produce an alloy of copper with 3 to 45 percent zinc, before zinc itself was understood as a distinct element.

Georgius Agricola formalised blende in print in 1546. Various chemical-based names followed over the next three centuries, including zincum. Vernacular names piled up too: zinc blende, black-jack, ruby blende.

In 1847, the German mineralogist Ernst Friedrich Glocker drew the modern scientific name from the Greek sphaleros, meaning treacherous.

Industrial & practical applications

Roughly 95 percent of the world's primary zinc starts as sphalerite. The mineral is the chief ore of zinc — the source from which everything downstream is made.

Most of that zinc ends up coating other metals against corrosion. Galvanising layers it onto steel, giving sheet metal and structural shapes their rust-resistant surface. Smaller shares go into brass and into dry-cell batteries.

Sphalerite is also the principal source of several quieter metals. Cadmium, gallium, germanium, and indium substitute for zinc in the crystal lattice and are recovered as by-products of zinc refining.

Where it forms, where it's found

22,109recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Resinous
Transparency
Transparent · Translucent
Colour
Mostly light to dark brown to black · . Less commonly red · red-brown · colourless · light blue · or green

Coloration of sphalerites from the Binntal, CH - varying from yellow to black for nearly identical iron contents - seems to be strongly influenced by the manganese content (Graeser, 1969).

Streak
Pale yellow to brown.
Tenacity
brittle
Cleavage
Perfect

Perfect (011)

Fracture
Conchoidal
Density
3.9 g/cm³

Optical

Optical type
Isotropic
Refractive index
2.369
Surface relief
Very high
Principal indices
nα 2.369
Birefringence
May show strain induced birefringence
Pleochroism
Non-pleochroic
Optical colour
Medium gray
Internal reflections
White, yellow, red, brown
Tropism
Isotropic
Reflectance R%
(19.6) 400, (19.0) 420, (18.3) 440, (17.9) 460, (17.5) 480, (17.2) 500, (16.9) 520, (16.7) 540, (16.5) 560, (16.4) 580, (16.3) 600, (16.2) 620, (16.1) 640, (16.0) 660, (15.9) 680, (15.8) 700
Luminescence
Fluorescent and triboluminescent
UV response
Light colored sphalerite may fluoresce in blue or orange in LW. Fluoresces less strongly, sometimes not at all, in SW or MW.
Reflected-light panel
17.0 %isotropic · single curve
Specimen sRGB 150, 105, 60
White reference100 % reflector under same lamp
Reflected colour
Medium gray
Internal reflections
White, yellow, red, brown

Crystallography

Crystal system
Isometric
Space group
#208
Cell parameters
a = 5.406 Å
Z
4
Twinning

(111)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc165.38065.380
67.10%
16SSulfurSulfur132.06032.060
32.90%
Total97.440100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Mn
  • Cd
  • Hg
  • In
  • Tl
  • Ga
  • Ge
  • Sb
  • Sn
  • Pb
  • Ag
  • Co

Synonyms

  • Beta zinc sulfide
  • Blackjack Zinc
  • Blende
  • Brunckit
  • Brunkit
  • False Galena
  • Garnet Blende
  • Granat-Blende
  • Marasmolit
  • Marasmolite
  • Pseudogalena
  • Ruby Blende
  • Ruby Zinc
  • Wild Lead
  • Zinc Blende

In other languages

French
Blende · Calaem · Christophite · Chrystophite · Marasmolite · Pseudo-galène · sphalérite · Zinc sulfuré · Zinc-blende
German
Sphalerit · Sphalerith · Zinkblende
Spanish
blenda · cincblenda · Esfalerita · zincblenda
Italian
Blenda · Sfalerite · Zincoblenda
Portuguese
blenda · Esfalerita · Esfalerite
Japanese
スファレライト · セン亜鉛鉱 · 閃亜鉛鉱
Chinese
閃鋅礦
Simplified Chinese
闪锌矿
Traditional Chinese
閃鋅礦
Russian
Медовая обманка · Рубиновая обманка · Сфалерит · Цинковая обманка
Arabic
السفاليريت · سفاليريت

Classification

Strunz
10th ed.

2.CB.05a

  • 2Sulfides and SulfosaltsClass
  • 2.CMetal Sulfides, M: S = 1: 1 (and similar)Division
  • 2.CBWith Zn, Fe, Cu, Ag, etc.Group
  • 2.CB.05aSphaleriteSpecies
Dana
8th ed.

02.08.02.01

  • 02SulfidesClass
  • 02.08AmXp, with m:p = 1:1Type
  • 02.08.02Sphalerite Group (Isometric: F4-3m)Group
  • 02.08.02.01SphaleriteSpecies
CIM

3.4.4

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.4Sulphides etc. of Group II metals other than Hg (Mg, Ca, Zn, Cd)Group
  • 3.4.4SphaleriteSpecies

Group, growth & confusion

In the same group
8 members
Often grow together
61 minerals
Commonly confused with
3 minerals

Literature, links & citation

Citations
  1. De natura fossilium - Lib. I-X
  2. Schroll, E. (1953): Über Unterschiede im Spurengehalt bei Wurtziten, Schalenblenden und Zinkblenden. Sitzungsber. Österr. Akad. Wiss. Wien, math.-naturwiss. Kl., 162, 305-332.
  3. 1747Wallerius (1747) 248.
  4. 1782Bergmann (1782).
  5. 1847Glocker, Ernst Friedrich (1847) Generum et specierum mineralium, secundum ordines naturales digestorum synopsis, omnium, quotquot adhuc reperta sunt, mineralium nomina complectens [A synopsis of the genera and species of minerals, according to their natural orders, including the names of all the minerals that have yet been discovered.]. Eduardus Anton. 348 pp.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Sphalerite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/sphalerite-3727},
  note      = {Accessed 2026-05-11}
}