Ponomarevite

K4Cu4OCl10
IMA status
  • Approved
IMA symbol
Pon
Discovered
1988
Also known as
  • IMA1986-040
  • Ponomareviet

Where it forms, where it's found

Geological setting

Fumarole

Type locality
First scoria cone
  1. Northern Breakthrough (North Breach)
  2. Great Fissure eruption (Main Fracture)
  3. Tolbachik Volcanic field
  4. Milkovsky District
  5. Kamchatka Krai
  6. Russia

55.6815°, 160.2373°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Red with a gold tint
Streak
Orange-red
Tenacity
brittle
Cleavage
Imperfect/Fair

Parallel to (001), also (110)

Optical

Optical type
Biaxial (-) · 2V measured = 28° · 2V calc = 26°
Refractive index
1.686 – 1.72
Surface relief
High
Principal indices
nα 1.686 · nβ 1.718 · nγ 1.72
Pleochroism
Non-pleochroic
Dispersion
r > v
Extinction
Y = b; X ∧ c = 30◦
Michel-Lévy diagramhighlighted lineδ = 0.0340
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]340 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation340 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 14.740(3) Å · b = 14.900(3) Å · c = 8.948(2) Å
Cell angles
β = 104.9(1) °
Ratio a:b:c
1 : 1.011 : 0.607
Z
4
Morphology

Pseudohexagonal plates with (104) and (010) pinacoids and (530) prism.

Type-locality form

Cement and as a crust, 1-2 cm in thickness, having nodular (0.1 to 0.3 cm in diameter) and skeletal forms. Microscopic psuedohexagonal plates.

Comment

Data from Semenova, et al. (1989)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
17ClChlorineChlorine1035.450354.500
45.39%
29CuCopperCopper463.546254.184
32.54%
19KPotassiumPotassium439.098156.392
20.02%
8OOxygenOxygen115.99915.999
2.05%
Total781.075100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1986-040
  • Ponomareviet

In other languages

German
IMA 1986-040 · Ponomarevit
Italian
Ponomarevite

Classification

Strunz
10th ed.

3.DA.35

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DAWith Cu, etc., without PbGroup
  • 3.DA.35PonomareviteSpecies
Dana
8th ed.

10.06.12.01

  • 10Oxyhalides and HydroxyhalidesClass
  • 10.06AmBn(O,OH)pXqType
  • 10.06.12— unnamed intermediate level —Group
  • 10.06.12.01PonomareviteSpecies
CIM

8.2.13

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.2Halides of CuGroup
  • 8.2.13PonomareviteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1972de Boer, J.J., Bright, D., Helle, J.N. (1972) The structure of the potassium salt of μ4-oxo-hexa-μ-chloro-tetra[chlorocuprate(II)], K4Cu4OCl10. Acta Crystallographica: B28: 3436-3437.
  2. 1988Vergasova L P, Filatov S K, Serafimova E K, Semenova T F (1988) Ponomarevite K4Cu4OCl10 - a new mineral from volcanic sublimates, Doklady Akademii Nauk SSSR 300, 1197-1200
  3. 1989Semenova, T.F., Rozhdestvenskaya, I.V., Filatov, S.K., Verasova, L.P. (1989) Crystal structure of a new mineral ponomarevite, K4Cu4OCl10. Doklady Akademii Nauk SSSR: 304: 427-430.
  4. 1990Jambor, John L., Vanko, David A. (1990) New Mineral Names. American Mineralogist, 75 (5-6) 706-713
  5. 2005Boller, H., Dilshad, R., Klepp, K. (2005) Ponomarevite, K4Cu4OCl10, a naturally occurring mineral with a [Cu4O] core - ancestor of many synthetic cluster compounds. Acta Crystographica: A61: C376.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ponomarevite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ponomarevite-3263},
  note      = {Accessed 2026-05-11}
}