Poppiite

Ca2V3+V3+2(Si2O7)(SiO4)(OH,O)2 · H2O
IMA status
  • Approved
IMA symbol
Pop
IMA approved
2005
Also known as
  • IMA2005-018
  • Poppiiet
  • UM1992-34-SiO:AlCaFeMgV

Where it forms, where it's found

Geological setting

Manganese deposit

Type locality
Gambatesa Mine
  1. Reppia
  2. Ne
  3. Genoa
  4. Liguria
  5. Italy

44.3597°, 9.4500°

4recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Brown to greenish brown
Streak
Greenish white
Tenacity
brittle
Cleavage
Very Good

(100) and (001)

Fracture
Sub-Conchoidal
Density
3.36 g/cm³

Optical

Optical type
Biaxial (-) · 2V calc = 44°
Refractive index
1.768 – 1.81
Surface relief
High
Principal indices
nα 1.768 · nβ 1.804 · nγ 1.810
Pleochroism
Visible

α = light yellowish brown ß = deep greenish brown γ = brown to reddish brown

UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0420
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]420 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation420 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 19.2889(6) Å · b = 6.0444(2) Å · c = 8.8783(3) Å
Cell angles
β = 97.328(2) °
Ratio a:b:c
1 : 0.313 : 0.460
Unit cell volume
1026.66 ų
Morphology

Minute (0.1 to 0.6 mm) prismatic crystals.

Twinning

Sometimes polysynthetic twinning

Type-locality form

minute prismatic crystals up to 0.6 mm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
44.34%
23VVanadiumVanadium350.942152.826
26.47%
14SiSiliconSilicon328.08584.255
14.60%
20CaCalciumCalcium240.07880.156
13.89%
1HHydrogenHydrogen41.0084.032
0.70%
Total577.253100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2005-018
  • Poppiiet
  • UM1992-34-SiO:AlCaFeMgV

In other languages

German
IMA 2005-018 · Poppiit
Italian
poppiite

Classification

Strunz
10th ed.

9.BG.20

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BGSorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordinationGroup
  • 9.BG.20PoppiiteSpecies

Group, growth & confusion

In the same group
1 members

Literature, links & citation

Citations
  1. 2004Caprilli, E. (2004) Miche e cloriti: implicazioni cristallochimiche. PhD thesis, University of Modena and Reggio Emilia: 205 pp.
  2. 2005Caprilli, E. (2005) Micas and chlorites: crystal chemical implications. Plinius, 31. 65-70
  3. 2006Brigatti, M. F., Caprilli, E., Marchesini, M. (2006) Poppiite, the V3+ end-member of the pumpellyite group: Description and crystal structure. American Mineralogist, 91 (4) 584-588 doi:10.2138/am.2006.2033 DOI: 10.2138/am.2006.2033
  4. 2018Nagashima, Mariko, Matsumoto, Takashi, Yamada, Takashi, Takizawa, Minoru, Momma, Koichi (2018) Crystal chemistry of poppiite, V–analogue of pumpellyite, from the Komatsu mine, Saitama Prefecture, Japan. Journal of Mineralogical and Petrological Sciences, 113 (5). 251-262 doi:10.2465/jmps.180613 DOI: 10.2465/jmps.180613
  5. 2022(2022) Poppiite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Poppiite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/poppiite-27576},
  note      = {Accessed 2026-05-11}
}