Posnjakite

Cu4(SO4)(OH)6 · H2O
IMA status
  • Approved
IMA symbol
Pnk
Discovered
1967
Also known as
  • IMA1967-001

Where it forms, where it's found

Geological setting

Secondary mineral from oxidized chalcopyrite.

Type locality
Nura-Taldy W deposit
  1. Shet District
  2. Karaganda Region
  3. Kazakhstan

49.1317°, 73.4781°

329recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous.
Transparency
Translucent
Colour
Sky-blue to dark-blue · may be slightly greenish-blue.
Streak
Pale-blue.
Tenacity
brittle
Cleavage

None?

Density
3.32 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 57° · 2V calc = 66°
Refractive index
1.625 – 1.706
Surface relief
High
Principal indices
nα 1.625 · nβ 1.68 · nγ 1.706
Pleochroism
Visible

X = bluish to colorless, Y = blue to dark blue, Z = greenish blue to blue.

Dispersion
r < v moderate
Notes

Absorption: Y >> Z > X.

Michel-Lévy diagramhighlighted lineδ = 0.0810
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]810 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation810 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#6
Cell parameters
a = 10.578(5) Å · b = 6.345(3) Å · c = 7.863(3) Å
Cell angles
β = 117.98(5) °
Ratio a:b:c
1 : 0.600 : 0.743
Unit cell volume
466.06 ų
Z
2
Morphology

Thin rhombic plates; dominant (101) with (110), (111), (010), (231), (001), (323) and (100). Prismatic; dominant (100), (010) with (001), and (101).

Twinning

Frequent on (110).

Type-locality form

Small grains, small tabular crystals up to 0.2-0.5 mm., and as films on fissures in quartz and fluorite.

Comment

Reduced cell is 6.345, 7.863, 9.781 A, 107.247, 90, 89.999°.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper463.546254.184
54.05%
8OOxygenOxygen1115.999175.989
37.42%
16SSulfurSulfur132.06032.060
6.82%
1HHydrogenHydrogen81.0088.064
1.71%
Total470.297100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1967-001

In other languages

French
Posnjakite
German
IMA 1967-001 · Posnjakit
Spanish
Posnjakita
Italian
Posnjakite

Classification

Strunz
10th ed.

7.DD.10

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DDWith only medium-sized cations; sheets of edge-sharing octahedraGroup
  • 7.DD.10PosnjakiteSpecies
Dana
8th ed.

31.04.01.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.04(AB)4(XO4)Zq·xH2OType
  • 31.04.01— unnamed intermediate level —Group
  • 31.04.01.01PosnjakiteSpecies
CIM

25.2.8

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.8PosnjakiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1967Fleischer, M. (1967) New Mineral Names. American Mineralogist, 52 (9-10) 1579-1589
  2. 1967Komkov, A.I., Nefedov, E.I. (1967) Posnjakite, a new mineral. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 96: 1: 58-62.
  3. 1970Knight, J. R., Barstow, R. W. (1970) Posnjakite from Cornwall. Mineralogical Magazine, 37 (290) 740 doi:10.1180/minmag.1970.037.290.19 DOI: 10.1180/minmag.1970.037.290.19
  4. 1971Nechiporenko, G.O. (1971) On the synthetic posnjakite. Proceedings of the Russian Mineralogical Society: 100: 754-756.
  5. 1979Mellini, M., Merlino, S. (1979) Posnjakite: 2∞[Cu4(OH)6(H2O)O] octahedral sheets in its structure. Zeitschrift für Kristallographie - Crystalline Materials, 149 (14) 249-257 doi:10.1524/zkri.1979.149.14.249 DOI: 10.1524/zkri.1979.149.14.249
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Posnjakite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/posnjakite-3265},
  note      = {Accessed 2026-05-11}
}