Puninite

Na2Cu3O(SO4)3
IMA status
  • Approved
IMA symbol
Pun
IMA approved
2015
Also known as
  • IMA2015-012
  • Puniniet

Where it forms, where it's found

Geological setting

Fumarole at 320°C.

Type locality
Glavnaya Tenoritovaya fumarole (Major Tenorite)
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Emerald green
Streak
Greenish
Tenacity
brittle
Cleavage
Perfect

On (100)

Fracture
Irregular/Uneven
Density
3.284 g/cm³

Optical

Optical type
Biaxial (+) · 2V calc = 80.7°
Refractive index
1.562 – 1.634
Surface relief
Moderate
Principal indices
nα 1.562 · nβ 1.591 · nγ 1.634
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0720
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]720 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation720 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 17.41(1) Å · b = 9.39(1) Å · c = 14.40(1) Å
Cell angles
β = 112.04(7) °
Ratio a:b:c
1 : 0.539 : 0.827
Unit cell volume
2183 ų
Z
8
Type-locality form

As crystalline crusts, individual crystals up to 10 x 30 x 50 µm (usually 5-20 µm) in size, and as irregularly shaped grains.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1315.999207.987
38.46%
29CuCopperCopper363.546190.638
35.25%
16SSulfurSulfur332.06096.180
17.79%
11NaSodiumSodium222.99045.980
8.50%
Total540.785100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2015-012
  • Puniniet

In other languages

German
IMA 2015-012 · Puninit
Italian
puninite

Classification

Strunz
10th ed.

7.BC.20

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BCWith medium-sized and large cationsGroup
  • 7.BC.20PuniniteSpecies

Group, growth & confusion

In the same group
1 members

Literature, links & citation

Citations
  1. 2015Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2015) New minerals and nomenclature modifications approved in 2015, CNMNC Newsletter 26. Mineralogical Magazine, 79 (4) 941-947 doi:10.1180/minmag.2015.079.4.05DOI: 10.1180/minmag.2015.079.4.05
  2. 2017Siidra, Oleg I., Nazarchuk, Evgenii V., Zaitsev, Anatoly N., Lukina, Evgeniya A., Avdontseva, Evgeniya Y., Vergasova, Lidiya P, Vlasenko, Natalia S., Filatov, Stanislav K., Turner, Rick, Karpov, Gennady A. (2017) Copper oxosulphates from fumaroles of Tolbachik volcano: puninite, Na2Cu3O(SO4)3 – a new mineral species and structure refinements of kamchatkite and alumoklyuchevskite. European Journal of Mineralogy, 29 (3) 499-510 doi:10.1127/ejm/2017/0029-2619 DOI: 10.1127/ejm/2017/0029-2619
  3. 2017Siidra, Oleg (2017) Erratum: Copper oxosulphates from fumaroles of Tolbachik volcano: puninite, Na2Cu3O(SO4) – a new mineral species and structure refinements of kamchatkite and alumoklyuchevskite by Oleg I. Siidra et al. (2017, vol. 29, p. 499–510, DOI: 10.1127/ejm/2017/0029-2619) European Journal of Mineralogy, 29 (6) 1089 doi:10.1127/ejm/2017/0029-2705DOI: 10.1127/ejm/2017/0029-2705
  4. 2020(2020) Puninite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Puninite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/puninite-46673},
  note      = {Accessed 2026-05-11}
}