Rouaite

Cu2(NO3)(OH)3
IMA status
  • Approved
IMA symbol
Rou
Also known as
  • IMA1999-010
  • Rouaiet

Where it forms, where it's found

Type locality
Roua Mines (Clue de Roua)
  1. Daluis
  2. Nice Arrondissement
  3. Alpes-Maritimes
  4. Provence-Alpes-Côte d'Azur
  5. France

44.0304°, 6.8677°

16recorded occurrences
Source · OpenStreetMap

Physical

Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Dark emerald-green
Streak
clear green
Tenacity
brittle
Cleavage
Perfect

Perfect on (001), and rarely macled by contact on (100)

Density
3.38 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 81° · 2V calc = 80°
Refractive index
1.7 – 1.738
Surface relief
High
Principal indices
nα 1.700 · nβ 1.715 · nγ 1.738
Birefringence
0.038
Pleochroism
Visible

X = dark blue-green, Y = blue-green, Z = pale-green

Dispersion
r > v strong
UV response
Not fluorescent in UV
Notes

Dispersion very strong

Michel-Lévy diagramhighlighted lineδ = 0.0380
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]380 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation380 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#9
Cell parameters
a = 5.596(2) Å · b = 6.079(2) Å · c = 6.925(3) Å
Cell angles
β = 94.67(2) °
Ratio a:b:c
1 : 1.086 : 1.237
Z
2
Morphology

Tabular on (001) or equant.

Comment

Commonly twinned on (001).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper263.546127.092
52.93%
8OOxygenOxygen615.99995.994
39.98%
7NNitrogenNitrogen114.00714.007
5.83%
1HHydrogenHydrogen31.0083.024
1.26%
Total240.117100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1999-010
  • Rouaiet

In other languages

German
IMA 1999-010 · Rouait
Italian
Rouaite

Classification

Strunz
10th ed.

5.NB.05

  • 5CarbonatesClass
  • 5.NNITRATESDivision
  • 5.NBWith OHGroup
  • 5.NB.05RouaiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1961Oswald, H. R. (1961) Über natürlichen und künstlichen Gerhardtit. Zeitschrift für Kristallographie - Crystalline Materials, 116 (3) 210-219 doi:10.1524/zkri.1961.116.3-6.210 DOI: 10.1524/zkri.1961.116.3-6.210
  2. 1983Effenberger, H. (1983) Verfeinerung der Kristallstruktur des monoklinen Dikupfer(II)-trihydroxi-nitrates Cu2(NO3)(OH)3. Zeitschrift für Kristallographie, 165 (1). 127-135 doi:10.1524/zkri.1983.165.1-4.127 DOI: 10.1524/zkri.1983.165.1-4.127
  3. 1994Guillou, N., Louër, M., Louër, D. (1994) An X-Ray and Neutron Powder Diffraction Study of a New Polymorphic Phase of Copper Hydroxide Nitrate. Journal of Solid State Chemistry, 109. 307-314 doi:10.1006/jssc.1994.1108DOI: 10.1006/jssc.1994.1108
  4. 1994Guillou, N., Louër, M., Louër, D. (1994) High Temperature X-Ray and Neutron Powder Diffraction Study of a Phase Transition in Copper Hydroxide Nitrate. Materials Science Forum, 166. 559-564 doi:10.4028/www.scientific.net/msf.166-169.559DOI: 10.4028/www.scientific.net/msf.166-169.559
  5. 2001Sarp, H., Černý, R. & Guenee, L. (2001): Rouaite, Cu2(NO3)(OH)3, un nouveau minéral: sa description et sa structure cristalline (Alpes-Maritimes, France). Riv. Scientifique 85, 3-12 (in French).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Rouaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/rouaite-10588},
  note      = {Accessed 2026-05-11}
}