Russoite

(NH4)ClAs2O3(H2O)0.5
IMA status
  • Approved
IMA symbol
Rso
IMA approved
2016
Also known as
  • IMA2015-105
  • Russoiet

Where it forms, where it's found

Geological setting

Fumarole

Type locality
"Bocca Grande" fumarole
  1. Solfatara di Pozzuoli
  2. Pozzuoli
  3. Metropolitan City of Naples
  4. Campania
  5. Italy

40.8281°, 14.1417°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent · Translucent
Colour
Colorless · yellowish
Streak
White
Tenacity
brittle
Cleavage
Perfect

On (001)

Fracture
Irregular/Uneven
Density
2.89 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.65 – 1.81
Surface relief
High
Principal indices
nω 1.810 · nε 1.650
UV response
Does not fluoresce
Michel-Lévy diagramhighlighted lineδ = 0.1600
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1600 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1600 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#118
Cell parameters
a = 5.2411(7) Å · c = 12.5948(25) Å
Unit cell volume
299.62 ų
Z
2
Morphology

Hexagonal plates flattened on (001) and bounded by (100).

Twinning

None observed

Type-locality form

Hexagonal plates up to about 300μm in diameter and 15μm thick, in rosette-like intergrowths.

Comment

Space group may be incorrect - the synthetic compound has space group P6/mmm (Wrześniewska et al., 2023).

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic274.922149.844
57.56%
8OOxygenOxygen3.515.99955.997
21.51%
17ClChlorineChlorine135.45035.450
13.62%
7NNitrogenNitrogen114.00714.007
5.38%
1HHydrogenHydrogen51.0085.040
1.93%
Total260.338100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2015-105
  • Russoiet

In other languages

German
IMA 2015-105 · Russoit

Classification

Strunz
10th ed.

3.DC.05

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DCWith Pb (As,Sb,Bi), without CuGroup
  • 3.DC.05RussoiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2016Hålenius, U., Hatert, F., Pasero, M., Mills, S.J. (2016) New minerals and nomenclature modifications approved in 2016, CNMNC Newsletter no 30. Mineralogical Magazine, 80 (2) 407-413 doi:10.1180/minmag.2016.080.081DOI: 10.1180/minmag.2016.080.081
  2. 2019Campostrini, Italo, Demartin, Francesco, Scavini, Marco (2019) Russoite, NH4ClAs23+O3(H2O)0.5, a new phylloarsenite mineral from Solfatara Di Pozzuoli, Napoli, Italy. Mineralogical Magazine, 83 (1) 89-94 doi:10.1180/minmag.2017.081.097DOI: 10.1180/minmag.2017.081.097
  3. 2020(2020) Russoite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2023Wrześniewska, W., Paluch, P. & Guńka, P. A. (2023): Arsenic(III) oxide intercalate with ammonium chloride: crystal structure revision and thermal characterization. Acta Crystallogr. B79: 207-212.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Russoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/russoite-47596},
  note      = {Accessed 2026-05-11}
}